Concept explainers
(a)
Interpretation: Synthesis of the given compound from acetylene and other required reagents is to be devised.
Concept introduction: Terminal
The addition of
In presence of peroxide,
Answer to Problem 12.65P
Synthesis of the given compound from acetylene and other required reagents is shown below.
Explanation of Solution
Synthesis of the given compound is shown below.
Figure 1
In the first step, acetylene is converted to
Synthesis of the given compound from acetylene and other required reagents is shown in Figure 1.
(b)
Interpretation: Synthesis of the given compound from acetylene and other required reagents is to be devised.
Concept introduction: Terminal alkynes can be converted into internal alkynes by forming new
In presence of sodium metal in ammonia, the alkyne is reduced to
Answer to Problem 12.65P
Synthesis of the given compound from acetylene and other required reagents is shown below.
Explanation of Solution
Synthesis of the given compound is shown below.
Figure 2
In the first step, acetylene is converted to
In the final step,
In the final step,
Synthesis of the given compound from acetylene and other required reagents is shown in Figure 2.
(c)
Interpretation: Synthesis of the given compound from acetylene and other required reagents is to be devised.
Concept introduction: Terminal alkynes can be converted into internal alkynes by forming new
The addition of
Addition of two hydroxyl groups on double bond to form
Answer to Problem 12.65P
Synthesis of the given compound from acetylene and other required reagents is shown below.
Explanation of Solution
Synthesis of the given compound is shown below.
Figure 3
In the first step, acetylene is converted to
Synthesis of the given compound from acetylene and other required reagents is shown in Figure 3.
(d)
Interpretation: Synthesis of the given compound from acetylene and other required reagents is to be devised.
Concept introduction: Terminal alkynes can be converted into internal alkynes by forming new
The addition of
In presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. The weak pi bond of alkene and weak
Answer to Problem 12.65P
Synthesis of the given compound from acetylene and other required reagents is shown below.
Explanation of Solution
Synthesis of the given compound is shown below.
Figure 4
In the first step, acetylene is converted to
Synthesis of the given compound from acetylene and other required reagents is shown in Figure 4.
Want to see more full solutions like this?
Chapter 12 Solutions
Organic Chemistry
- Devise a synthesis of each compound from cyclopentane and any other required organic or inorganic reagents.arrow_forwardDevise a synthesis of each attached compound from cyclopentane and any other required organic or inorganic reagents.arrow_forwardDevise a synthesis of each compound from cyclohexene and any required organic or inorganic reagents.arrow_forward
- Devise a synthesis of each compound from benzene, any organic alcohols having four or fewer carbons, and any required reagents.arrow_forwardSynthesis 13.58 Devise a synthesis of each compound from cyclopentane and any other required organic or inorganic reagents. OH a. b. C. OH d. J OH CNarrow_forwardDevise a synthesis of each compound from cyclohexene and any required organic compounds or inorganic reagents.arrow_forward
- Devise a synthesis of A from the three starting materials given. You may use any other needed organic or inorganic reagents.arrow_forwardDevise a synthesis of each compound from phenol (C6H5OH) and any other organic or inorganic reagents.arrow_forwardDevise a synthesis of each biologically active compound from benzenearrow_forward
- Devise a synthesis of each compound from benzene.arrow_forwardDevise a synthesis of each compound from cyclohexene and organic alcohols. You may use any other required organic or inorganic reagents.arrow_forwardDevise a synthesis of each compound from benzene. You may usealcohols with one or two carbons and any inorganic reagents.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY