Organic Chemistry

5th Edition

ISBN: 9780078021558

Author: Janice Gorzynski Smith Dr.

Publisher: McGraw-Hill Education

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Chapter 12, Problem 12.58P

Epoxidation of the following allylic alcohol using the Sharpless reagent with ( − ) -DET gives two epoxy alcohols in a ratio of 87 : 13 .

Chapter 12, Problem 12.58P, 12.58 Epoxidation of the following allylic alcohol using the Sharpless reagent with gives two epoxy

a. Assign structures to the major and minor product.

b. What is the enantiomeric excess in this reaction?

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Chapter 12, Problem 12.57P

Chapter 12, Problem 12.59P

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Chapter 12 Solutions

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Epoxidation of the following allylic alcohol using the Sharpless reagent with ( − ) -DET gives two epoxy alcohols in a ratio of 87 : 13 . a. Assign structures to the major and minor product. b. What is the enantiomeric excess in this reaction?

Solution Summary: The author explains the structure of major and minor products obtained by Sharpless epoxidation.

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