Concept explainers
Interpretation:
The interplanar distance of the metallic crystal has to be determined.
Concept introduction:
The structure of a crystalline solid can be determined by X-ray diffraction method using the Bragg equation,
Where,
Bragg equation was derived from Bragg’s law which states –
“When X-ray is incident onto a crystal surface, the angle of incidence
Want to see the full answer?
Check out a sample textbook solutionChapter 12 Solutions
Chemistry: Atoms First
- Calcium oxide consists of a face-centered cubic array of O2 ions, with Ca2+ ions at the center of the unit cell and along the centers of all 12 edges. Calculate the number of each ion in the unit cell.arrow_forwardPalladium has a cubic crystal structure in which the edge of the unit cell is 389 pm long. If the density of palladium is 12.02 g/cm3, how many palladium atoms are in a unit cell? In which of the cubic unit cells does palladium crystallize?arrow_forwardThe CsCl structure is a simple cubic array of chloride ions with a cesium ion at the center of each cubic array (see Exercise 69). Given that the density of cesium chloride is 3.97 g/cm3, and assuming that the chloride and cesium ions touch along the body diagonal of the cubic unit cell, calculate the distance between the centers of adjacent Cs+ and Cl ions in the solid. Compare this value with the expected distance based on the sizes of the ions. The ionic radius of Cs+ is 169 pm, and the ionic radius of Cl is 181 pm.arrow_forward
- Arrange the following substances in order of increasing strength of the crystal forces: He, NH3, NO2, NaBr, BaO. Identify the kinds of forces that are most important in holding the particles together in a crystalline solid sample of each of the following substances. (a) H2O (b) C6H6 (c) CaCl2 (d) SiO2 (e) Fearrow_forwardA portion of the crystalline lattice for potassium is illustrated below. (a) In what type of unit cell are the K atoms arranged? A portion of the solid-state structure of potassium. (b) If one edge of the potassium unit cell is 533 pm, what is the density of potassium?arrow_forwardSpinel is a mineral that contains 37.9% aluminum, 17.1% magnesium, and 45.0% oxygen, by mass, and has a density of 3.57 g/cm3.The edge of the cubic unit cell measures 809 pm. How many of each type of ion are present in the unit cell?arrow_forward
- Describe, in general, the structures of ionic solids. Compare and contrast the structure of sodium chloride and zinc sulphide. How many tetrahedral holes and octahedral holes are there per closest packed anion? In zinc sulphide, why are only one-half of the tetrahedral holes filled with cations?arrow_forwardSilicon carbide, SiC, is a very hard, high-melting solid. What kind of crystal forces account for these properties?arrow_forwardThe unit cell of silicon carbide, SiC, is illustrated below. (a) In what type of unit cell are the (dark gray) C atoms arranged? (b) If one edge of the silicon carbide unit cell is 436.0 pm, what is the calculated density of this compound? A portion of the solid-state structure of silicon carbide.arrow_forward
- Crystalline polonium has a primitive cubic unit cell, lithium has a body-centered cubic unit cell, and calcium has a face-centered cubic unit cell. How many Po atoms belong to one unit cell? How many Li atoms belong to one unit cell? How many Ca atoms belong to one unit cell? Draw each unit cell. Indicate on your drawing what fraction of each atom lies within the unit cell.arrow_forwardThe surface tension and viscosity of water at several different temperatures are given in this table. Water Surface Tension (mN/m) Viscosity (mPa s) 0 C 75.6 1.79 20 C 72.8 1.00 60 C 66.2 0.47 100 C 58.9 0.28 (a) As temperature increases, what happens to the surface tension of water? Explain why this occurs, in terms of molecular interactions and the effect of changing temperature. (b) As temperature increases, what happens to the viscosity of water? Explain why this occurs, in terms of molecular interactions and the effect of changing temperature.arrow_forwardWhich of the following do you expect to be molecular solids? a silicon tetrachloride, SiCl4 b lithium bromide, LiBr c sodium fluoride, NaF d bromine chloride, BrClarrow_forward
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningPrinciples of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning