The oxidation of thallium(I) ion by cerium(IV) ion in aqueous solution has the equation
2 Ce4+(aq) + Tl+(aq) → 2 Ce3+(aq) + Tl3+(aq)
The accepted mechanism for this reaction is
- (a) Verify that this mechanism predicts the overall reaction.
- (b) Identify all intermediates in this mechanism.
- (c) Identify the catalyst in this mechanism.
- (d) Suppose that the first step in this mechanism is rate-limiting. Determine the rate law.
- (e) Suppose that the second step in this mechanism is rate-limiting. Determine the rate law.
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Chemistry: The Molecular Science
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