Organic Chemistry, Books a la Carte Edition (8th Edition)
Organic Chemistry, Books a la Carte Edition (8th Edition)
8th Edition
ISBN: 9780134074580
Author: Bruice, Paula Yurkanis
Publisher: PEARSON
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Chapter 11.5, Problem 23P

Draw the product of ring-closing metathesis for each of the following compounds:

Chapter 11.5, Problem 23P, Draw the product of ring-closing metathesis for each of the following compounds: , example  1

Chapter 11.5, Problem 23P, Draw the product of ring-closing metathesis for each of the following compounds: , example  2

Chapter 11.5, Problem 23P, Draw the product of ring-closing metathesis for each of the following compounds: , example  3

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Draw the main organic product(s) formed in each of the following reactions:
The following bicyclic ketone has two a-carbons and three a-hydrogens. When this molecule is treated with D,O in the presence of an acid catalyst, only two of the three a-hydrogens exchange with deuterium. The a-hydrogen at the bridgehead does not exchange. H these two a-hydrogens exchange H. this a-hydrogen does not exchange H How do you account for the fact that two a-hydrogens do exchange but the third does not? You will find it helpful to build models of the enols by which exchange of a-hydrogens occurs.
Draw the product of ring-closing metathesis for each of the following compounds:

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Organic Chemistry, Books a la Carte Edition (8th Edition)

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