Organic Chemistry, Books a la Carte Edition (8th Edition)
8th Edition
ISBN: 9780134074580
Author: Bruice, Paula Yurkanis
Publisher: PEARSON
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Question
Chapter 11, Problem 42P
(a)
Interpretation Introduction
Interpretation:
It should be identified for the unprepared compounds by using the Heck reaction.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of an
(b)
Interpretation Introduction
Interpretation:
The starting material and the suitable compound should be identified which can be prepared from Heck reaction.
Concept introduction:
Suzuki reaction:
A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.
Heck reaction:
A reaction that breaks the double bond of an alkene and then joins the fragments.
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a. Which of the following compounds cannot be prepared by a Heck reaction?b. For those compounds that can be prepared by a Heck reaction, what starting materials are required?
Which of the following compounds cannot be prepared by a Heck reaction? a. For those compounds that can be prepared by a Heck reaction, what starting materials are required?
A. OsO4 and NMO
B. Br2 and H20
C. Hg(OAc)2, H2O and NaBH4, NaOH
D. RCO3H
E. BH3-THF and H2O2, NaOH
Which reagent will complete this reaction?
Chapter 11 Solutions
Organic Chemistry, Books a la Carte Edition (8th Edition)
Ch. 11.1 - Prob. 1PCh. 11.2 - Which is more reactive an organolithium compound...Ch. 11.2 - Prob. 3PCh. 11.3 - Muscalure is the sex attractant of the common...Ch. 11.3 - Prob. 7PCh. 11.3 - Prob. 8PCh. 11.3 - Prob. 9PCh. 11.3 - Prob. 10PCh. 11.4 - Prob. 13PCh. 11.4 - Prob. 14P
Ch. 11.4 - Prob. 15PCh. 11.4 - Prob. 16PCh. 11.4 - Prob. 17PCh. 11.4 - Prob. 19PCh. 11.4 - Show how the Suzuki and/or Heck reactions can be...Ch. 11.4 - Identify two pairs of an alkyl bromide and an...Ch. 11.5 - Prob. 22PCh. 11.5 - Draw the product of ring-closing metathesis for...Ch. 11.5 - Prob. 25PCh. 11.5 - Prob. 26PCh. 11 - Prob. 27PCh. 11 - Prob. 28PCh. 11 - The coupling of an alkyne with an aryl halide in...Ch. 11 - Identify A through H.Ch. 11 - Using the given starting material, any necessary...Ch. 11 - What alkyl halide reacts with lithium...Ch. 11 - Prob. 33PCh. 11 - Prob. 34PCh. 11 - The following compound undergoes an intramolecular...Ch. 11 - Using ethynyleyclohexane as a starting material...Ch. 11 - Prob. 37PCh. 11 - Using the given starting material, any necessary...Ch. 11 - Prob. 39PCh. 11 - A student added an equivalent of...Ch. 11 - Using the given starting material, any necessary...Ch. 11 - Prob. 42PCh. 11 - Prob. 43PCh. 11 - Bombykol is the sex pheromone of the silk moth....Ch. 11 - Prob. 45PCh. 11 - Prob. 46PCh. 11 - A dibromide loses only one bromine when it reacts...Ch. 11 - What starting material is required in order to...Ch. 11 - What product is obtained from ring-opening...
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