Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Question
Chapter 1.13, Problem 35P
(a)
Interpretation Introduction
Interpretation:
The longer bond should be determined for given set of bonds.
(b)
Interpretation Introduction
Interpretation:
The stronger bond should be determined for given set of bonds.
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b. There is one additional resonance structure.
NH₂
c. There is a total of five resonance structures (including the original structure).
: OH
a. Which bond would be longer?
b. Which bond would be stronger?
1. C - Cl or C - I
2 C - C or C - Cl
3 H - Cl or H - F
12.
The three compounds depicted below are all FDA-approved drugs that contain sulfur.
How many bonds to sulfur in each compound?
Ph
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A. Penicillin G
B. Omeprazole
a. A:6 bonds, B:6 bonds, C:6 bonds
b. A:4 bonds, B:4 bonds, C:4 bonds
c. A:6 bonds, B:4 bonds, C:2 bonds
d. A:2 bonds, B: bonds, C:6 bonds
OCH3
H₂N
`N=N.
C. Prontosil
NH₂
NH₂
Chapter 1 Solutions
Organic Chemistry
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.1 - Chlorine has two isotopes, 35Cl and 37Cl; 75.77%...Ch. 1.2 - Prob. 3PCh. 1.2 - a. Write the ground-state electronic configuration...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar? a. b. c. d.Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...Ch. 1.3 - Explain why HCL has a smaller dipole moment than...
Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...Ch. 1.4 - Prob. 15PCh. 1.4 - a. Draw two Lewis structure for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 19PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 21PCh. 1.5 - Draw the following orbitals: a. 3s orbital b. 4s...Ch. 1.6 - Prob. 23PCh. 1.6 - Indicate the kind of molecular orbital (, , , or )...Ch. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.7 - Explain why a bond formed by overlap of s orbital...Ch. 1.9 - Put n number in each of the blanks: a. __ s...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 32PCh. 1.13 - a. What are the relative lengths and strengths of...Ch. 1.13 - Prob. 35PCh. 1.14 - Prob. 36PCh. 1.15 - Which of the bond in a carbon-oxygen double bond...Ch. 1.15 - Would you expect a CC bond formed by sp2sp2...Ch. 1.15 - Caffeine is a natural insecticide found in the...Ch. 1.15 - Prob. 41PCh. 1.15 - Predict the approximate bond angles for a. the CNC...Ch. 1.16 - If the dipole moment of CH3F is 1.847 D and the...Ch. 1.16 - Account for the difference in the shape and color...Ch. 1.16 - What of the following molecules would you expect...Ch. 1 - Prob. 46PCh. 1 - Prob. 47PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Draw the condensed structure of a compound that...Ch. 1 - Predict the approximate bond angles: a. the CNH...Ch. 1 - Prob. 51PCh. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - 53. What is the hybridization of each of the...Ch. 1 - Rank the bonds from most polar. a. CO, CF, CN b....Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Prob. 57PCh. 1 - Prob. 58PCh. 1 - Draw the missing lone-pair electrons and assigns...Ch. 1 - a. Which of the indicated bonds in each molecule...Ch. 1 - For each of the following molecules, indicate the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Rank the following compounds from highest dipole...Ch. 1 - In which orbitals are the lone pairs in nicotine?Ch. 1 - Prob. 65PCh. 1 - Prob. 66PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 68PCh. 1 - Which compound has a larger dipole moment: CH3Cl...Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - Explain why CH3Cl has a greater dipole moment than...Ch. 1 - Prob. 73P
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- hat does temperature measure? Are the molecules in a beaker of warm water moving at the same speed as the molecules in a beaker of cold water? Explain? What is heat? Is heat the same as temperature?arrow_forwardConsider the carbon-oxygen bond in formaldehyde (CH2O) and carbon monoxide (CO). In which molecule is the CO bond shorter? In which molecule is the CO bond stronger?arrow_forwardUsing the bond energies in Table 7.2, determine the approximate enthalpy change for each of the following reactions: (a) H2(g)+Br2(g)2HBr(g) (b) CH4(g)+I2(g)CH3I(g)+HI(g) (c) C2H4(g)+3O2(g)2CO2(g)+2H2O(g)arrow_forward
- Draw a curve that describes the energy of a system with H and Cl atoms at varying distances. Then, find the minimum energy of this curve two ways. (a) Use the bond energy found in Table 8.1 to calculate the energy for one single HCl bond (Hint: How many bonds are in a mole?) (b) Use the enthalpy of reaction and the bond energies for H2 and Cl2 to solve for the energy of one mole of HCl bonds. H2(g)+Cl2(g)2HCl(g)Hrxn=184.7kJ/molarrow_forwardArrange the highlighted bonds in the table below in decreasing order of polarity. That is, pick 1 for the most polar bond, pick 2 for the next most polar bond. and so on. bond polarity H. H. -C-H (Choose one) ▼ H-C-N (Choose one) H. H- C H. (Choose one) APR W I- CIH エー○arrow_forwardWhich type of bond exists in each compound? KCl a. polar covalent bonds b. ionic bonds c. nonpolar covalent bonds BCl3 a. ionic bonds b. polar covalent bonds c. nonpolar covalent bonds P4 a. nonpolar covalent bonds b. ionic bonds c. polar covalent bonds Br2 a. ionic bonds b. polar covalent bonds c. nonpolar covalent bonds CO a. polar covalent bonds b. ionic bonds c. nonpolar covalent bonds SO2 a. nonpolar covalent bonds b. ionic bonds c. polar covalent bondsarrow_forward
- What is the Lewis structure for chloroethylene (C 2H 3Cl)? OA. H H H-C=ċ-Cl: O B. H H H C-C-CI OC. H H H-C-C- O D. H H H-C=C-CIarrow_forwardChemistry Organize the following three molecules in order of increasing stability in water (least >arrow_forwardWith respect to C=C bond, which has a greater bond length? A. NEC-C C-H B.F-C = CH O Aarrow_forwardD. AH(reactants) 2 AH(products) 3. Which one of the following statements best describes the enthalpy change of a reaction? A. The energy released when chemical bonds are formed during a chemical reaction B. The energy consumed when chenical bonds are broken during a chemical reaction C. The difference between the energy released by bond formation and the energy consumed by bond cleavage during a chemical reaction. D. The increase in disorder of the system as a reaction proceeds.arrow_forwardChoose the best Lewis structure for CH2C12. H. a. H. 6. H–Cl–C-Cl-H H-H-C-Cl-Cl: H. Cl=c=Cl: d. Harrow_forward2. The Lewis structure for the acetate ion [C₂H3O2]¹ is given below: le a. Read section 1.9. What is the geometry (shape) around each of the carbon atoms in the acetate ion - tetrahedral, trigonal planar or linear? b. Each of the oxygen atoms in the acetate ion have an octet. Draw all lone pairs of electrons in the acetate ion given above. c. Read section 1.7. Use electron pushing to generate a resonance structure of the acetate Lewis structure given above.arrow_forwardarrow_back_iosSEE MORE QUESTIONSarrow_forward_ios
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