Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 11, Problem 17PS
Which member of each of the following pairs of compounds has the higher boiling point?
- (a) O2 or N2
- (b) SO2 or CO2
- (c) HF or HI
- (d) SiH4 or GeH4
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Which type of intermolecular force accounts for each of these differences? (a) CH3OH boils at 65 °C; CH3SH boils at 6 °C. (b) Xe is a liquid at atmospheric pressure and 120 K, whereas Ar is a gas under the same conditions. (c) Kr, atomic weight 84 amu, boils at 120.9 K, whereas Cl2, molecular weight about 71 amu, boils at 238 K. (d) Acetone boils at 56 °C, whereas 2-methylpropane boils at -12 °C.
CH3 CH3 O C CH3 CH3 CH3 CH Acetone 2-Methylpropane
Which of these molecules exhibits only the London dispersion forces (LDF) of interactions?
(A) H2O
(B) CO2
(C) SO2
(D) N2O
17. Which one of the following substances can be melted without breaking chemical bonds?
(a) sodium sulfate
(b) zinc chloride
(c) sulfur dioxide
(d) silicon dioxide
(e) diamond
Chapter 11 Solutions
Chemistry & Chemical Reactivity
Ch. 11.2 - Which should have the more negative hydration...Ch. 11.3 - Using structural formulas, describe the hydrogen...Ch. 11.4 - Prob. 11.3CYUCh. 11.5 - Prob. 11.4CYUCh. 11.6 - The molar enthalpy of vaporization of methanol,...Ch. 11.6 - Prob. 11.6CYUCh. 11.6 - Prob. 1.1ACPCh. 11.6 - Prob. 1.2ACPCh. 11.6 - Prob. 2.1ACPCh. 11.6 - Prob. 2.2ACP
Ch. 11 - Prob. 1PSCh. 11 - Intermolecular forces: What type of forces must be...Ch. 11 - Prob. 3PSCh. 11 - Prob. 4PSCh. 11 - Considering intermolecular forces in the pure...Ch. 11 - Considering intermolecular forces in the pure...Ch. 11 - Prob. 7PSCh. 11 - Which of the following compounds would be expected...Ch. 11 - Prob. 9PSCh. 11 - When salts of Mg2+, Na+, and Cs+ are placed in...Ch. 11 - Prob. 11PSCh. 11 - The enthalpy of vaporization of liquid mercury is...Ch. 11 - Answer the following questions using Figure 11.12:...Ch. 11 - Answer the following questions using Figure 11.12:...Ch. 11 - Prob. 15PSCh. 11 - Refer to Figure 11.12 to answer these questions:...Ch. 11 - Which member of each of the following pairs of...Ch. 11 - Place the following four compounds in order of...Ch. 11 - Prob. 19PSCh. 11 - You are comparing three different substances, A,...Ch. 11 - Equilibrium vapor pressures of benzene, C6H6, at...Ch. 11 - Prob. 22PSCh. 11 - Can carbon monoxide (Tc = 132.9 K; Pc = 34.5 atm...Ch. 11 - Methane (CH4) cannot be liquefied at room...Ch. 11 - What is surface tension? Give an example...Ch. 11 - What factors affect the viscosity of a substance?...Ch. 11 - If a piece of filter paper (an absorbent paper...Ch. 11 - When water is placed in a buret it forms a concave...Ch. 11 - Prob. 29GQCh. 11 - What types of intermolecular forces are important...Ch. 11 - Which of the following salts, Li2SO4 or Cs2SO4, is...Ch. 11 - Prob. 32GQCh. 11 - Prob. 33GQCh. 11 - Prob. 34GQCh. 11 - Rank the following compounds in order of...Ch. 11 - Prob. 36GQCh. 11 - Prob. 37GQCh. 11 - The following data are the equilibrium vapor...Ch. 11 - Prob. 39ILCh. 11 - A hand boiler can be purchased in toy stores or at...Ch. 11 - Prob. 41ILCh. 11 - Prob. 42ILCh. 11 - Acetone, CH3COCH3, is a common laboratory solvent....Ch. 11 - Cooking oil floats on top of water. From this...Ch. 11 - Liquid ethylene glycol, HOCH2CH2OH, is one of the...Ch. 11 - Liquid methanol, CH3OH, is placed in a glass tube....Ch. 11 - Account for these facts: (a) Although ethanol...Ch. 11 - Prob. 48SCQCh. 11 - Prob. 49SCQCh. 11 - Prob. 50SCQCh. 11 - Prob. 51SCQCh. 11 - Prob. 52SCQCh. 11 - A fluorocarbon, CF4, has a critical temperature of...Ch. 11 - Prob. 55SCQCh. 11 - List four properties of liquids that are directly...Ch. 11 - List the following ions in order of hydration...Ch. 11 - Prob. 59SCQCh. 11 - An 8.82-g sample of Br2 is placed in an evacuated...Ch. 11 - Polarizability is defined as the extent to which...Ch. 11 - Prob. 62SCQCh. 11 - A pressure cooker (a kitchen appliance) is a pot...Ch. 11 - Vapor pressures of NH3() at several temperatures...Ch. 11 - Prob. 65SCQCh. 11 - Prob. 66SCQCh. 11 - Prob. 67SCQ
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- Arrange each of the following sets of compounds in order of increasing boiling point temperature:(a) HCl, H2O, SiH4(b) F2, Cl2, Br2(c) CH4, C2H6, C3H8(d) O2, NO, N2arrow_forward(a) What are the C¬C¬C bond angles in diamond?(b) What are they in graphite (in one sheet)? (c) Whatatomic orbitals are involved in the stacking of graphitesheets with each other?arrow_forwardNaH crystallizes with the same crystal structure as NaCl. The edge length of the cubic unit cell of NaH is 4.880 Å.(a) Calculate the ionic radius of H−. (The ionic radius of Li+ is 0.0.95 Å.)(b) Calculate the density of NaH.arrow_forward
- Rank the following in order of decreasing(a) Boiling point: O₂, Br₂, As(s)(b) ΔH(vap): Cl₂, Ar, I₂arrow_forwardDoes SF₆(boiling point 16C at 1 atm) behave more ide-ally at 150C or at 20C? Explain.arrow_forwardName the type(s) of intermolecular forces that exists between molecules (or basic units) in each of the following species: (a) benzene (C6H6) (b) CH3Cl (c) PF3arrow_forward
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