Explanation Electrophilic substitution reactions in naphthalene: Fries rule: The most stable arrangement of a polynuclear compound is that form which has a maximum number of rings in the benzenoid condition. The most efficient stabilization of the intermediate carbocation produced by electrophilic attack on naphthalene comes from those resonance forms that retains one fully benzenoid ring. In case of 1-substitution, two structures can be obtained(A, B). In case of 2-substitution, one structure can be obtained(F). The intermediate from attack at the 1-position is more stable and therefore, the 1-substituted product is more favored in the electrophilic substitution of naphthalene. The carbocation formed by the attack of electrophile at 1-position of naphthalene is much more stabilize by resonance since it has four contributing structures in which aromatic character is retained in one of the ring...

7th Edition

ISBN: 9781319420994

Author: ATKINS

Publisher: MAC HIGHER

See similar textbooks

Concept explainers

Introduction to Organic Chemistry

The field of chemistry which deals with the studies of reactions, structures, and properties of organic compounds that comprise carbon bonded through covalent bonding is organic chemistry. The studies regarding the structure of organic compounds could be…

Vinyl Group

Vinyl group is the name given to the functional group of -CH=CH2. It can be seen as an ethene molecule with one less hydrogen in number. Hence it is also called as ethenyl group at times.

Straight Chain Hydrocarbons

The requirement to identify each compound needs a richer number of words than informative prefixes like n and iso. The identification of organic molecules is made easier by the use of systematic nomenclature schemes. The organic chemistry nomenclature ha…

Unsaturated Hydrocarbon

Following are few examples of alkenes with their general molecular as well as their structural formulas:

Conjugated Compounds in Organic Chemistry

The delocalization of electrons in a molecule is called conjugation in organic chemistry. This delocalisation process of electrons leads to the shortenings or elongations of chemical bonds, but at the same time it causes changes in the chemical propertie…

Alpha Carbon And Alpha Protons

The carbon directly attached to the functional group in an organic molecule is referred to as the alpha carbon and the hydrogen attached to an alpha carbon are termed as the alpha hydrogens or alpha protons. These alpha carbon atoms and alpha hydrogen at…

Question

Chapter 11, Problem 11C.9E

Interpretation Introduction

Interpretation:

The number of compounds that can be formed by electrophilic aromatic substitution reaction of naphthalene along with line structures has to be given.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Chapter 11, Problem 11C.8E

Chapter 11, Problem 11C.10E

Students have asked these similar questions

Give the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene Name the functional group: (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group:

5. Give the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group: Name the functional group:

Glucose, C6H12O6, contains an aldehyde group but exist predominantly in the form of the cyclic hemiacetal show below. A cyclic hemiacetal is formed when the —OH group of one carbon bonds to the carbonyl group of another carbon. Identify which carbon provides the —OH group and which provides the —CHO? Give a functional isomer of glucose and draw its structure.

Chapter 11 Solutions

CHEM PRINCIPLES LL W/ACHIEVE ONE-SEM

Ch. 11 - Prob. 11A.1AST Ch. 11 - Prob. 11A.1BST Ch. 11 - Prob. 11A.2AST Ch. 11 - Prob. 11A.2BST Ch. 11 - Prob. 11A.3AST Ch. 11 - Prob. 11A.3BST Ch. 11 - Prob. 11A.4AST Ch. 11 - Prob. 11A.4BST Ch. 11 - Prob. 11A.5AST Ch. 11 - Prob. 11A.5BST

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

The number of compounds that can be formed by electrophilic aromatic substitution reaction of naphthalene along with line structures has to be given.

Solution Summary: The author explains the number of compounds that can be formed by electrophilic aromatic substitution reaction of naphthalene along with line structures.

Concept explainers

Interpretation: The number of compounds that can be formed by electrophilic aromatic substitution reaction of naphthalene along with line structures has to be given.

Want to see the full answer?

Chapter 11 Solutions

Interpretation:

The number of compounds that can be formed by electrophilic aromatic substitution reaction of naphthalene along with line structures has to be given.