LCPO CHEMISTRY W/MODIFIED MASTERING
8th Edition
ISBN: 9780135214756
Author: Robinson
Publisher: PEARSON
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Chapter 11, Problem 11.4A
APPLY 11.2 Chloroform
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LCPO CHEMISTRY W/MODIFIED MASTERING
Ch. 11 - Prob. 11.1PCh. 11 - The normal boiling point of water is 100.0 C, and...Ch. 11 - PRACTICE 11.1 The boiling point of ethanol is 78.4...Ch. 11 - APPLY 11.2 Chloroform CHCl3 has Hvap=29.2kJ/mol...Ch. 11 - How much heat is required to convert15.0 g of...Ch. 11 - APPLY 11.4 What is the sign and magnitude of q...Ch. 11 - Look at the phase diagram of H2O in Figure 11.7,...Ch. 11 - Prob. 11.8ACh. 11 - Why was a new solvent needed for extracting...Ch. 11 - A fire extinguisher containing carbon dioxide has...
Ch. 11 - Look at the phase diagram of CO2 in Figure11.13,...Ch. 11 - Liquid carbon dioxide is also used as non-toxic...Ch. 11 - For the phase transition CO2(s)CO2(g), predict the...Ch. 11 - A sample of supercritical carbon dioxide was...Ch. 11 - Assume that you have a liquid in a cylinder...Ch. 11 - The phase diagram of a substance is shown below....Ch. 11 - Prob. 11.17CPCh. 11 - Prob. 11.18CPCh. 11 - The following compound undergoes a phase...Ch. 11 - A magnetized needle gently placed on the surface...Ch. 11 - Water flows quickly through the narrow neck of a...Ch. 11 - Predict which substance in each pair has the...Ch. 11 - Prob. 11.23SPCh. 11 - The chemical structure for oleic acid, the primary...Ch. 11 - Prob. 11.25SPCh. 11 - Prob. 11.26SPCh. 11 - The vapor pressure of SiCI4 is 100 mm Hg at 5.4 C,...Ch. 11 - What is the vapor pressure of CS2 in mm Hg at 20.0...Ch. 11 - What is the vapor pressure of SiCI4 in mm Hg at...Ch. 11 - Dichloromethane, CH2CI2, is an organic solvent...Ch. 11 - Prob. 11.31SPCh. 11 - Use the plot you made in Problem 11.30 to find a...Ch. 11 - Prob. 11.33SPCh. 11 - Prob. 11.34SPCh. 11 - Prob. 11.35SPCh. 11 - Prob. 11.36SPCh. 11 - Acetone,acommon laboratorysolvent,has...Ch. 11 - Why is Hvap usually larger than Hfusion ?Ch. 11 - Why is the heat of sublimation, Hsubl, equal to...Ch. 11 - Naphthalene, better known as "mothballs," has bp =...Ch. 11 - Prob. 11.41SPCh. 11 - Prob. 11.42SPCh. 11 - Prob. 11.43SPCh. 11 - Prob. 11.44SPCh. 11 - Prob. 11.45SPCh. 11 - How much energy in kilojoules is needed to heat...Ch. 11 - Prob. 11.47SPCh. 11 - How much energy in kilojoules is released when...Ch. 11 - How much energy in kilojoules is released when...Ch. 11 - Prob. 11.50SPCh. 11 - Prob. 11.51SPCh. 11 - Prob. 11.52SPCh. 11 - Prob. 11.53SPCh. 11 - Prob. 11.54SPCh. 11 - Look at the phase diagram of H2O in Figure 11.7,...Ch. 11 - Prob. 11.56SPCh. 11 - Oxygen has Tt=54.3K,Pt=1.14mmHg,Tc=154.6K, and...Ch. 11 - Prob. 11.58SPCh. 11 - Prob. 11.59SPCh. 11 - Prob. 11.60SPCh. 11 - Prob. 11.61SPCh. 11 - Benzene has a melting point of 5.53 C and a...Ch. 11 - Prob. 11.63SPCh. 11 - How many phase transitions did you pass through in...Ch. 11 - Prob. 11.65SPCh. 11 - Prob. 11.66SPCh. 11 - Prob. 11.67SPCh. 11 - Prob. 11.68SPCh. 11 - Prob. 11.69SPCh. 11 - Prob. 11.70SPCh. 11 - Prob. 11.71SPCh. 11 - Prob. 11.72SPCh. 11 - Prob. 11.73SPCh. 11 - For each of the following substances, identify the...Ch. 11 - The chlorofluorocarbon refrigerant...Ch. 11 - Prob. 11.76MPCh. 11 - Prob. 11.77MP
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- The cooling effect of alcohol on the skin is due to its evaporation. Calculate the heat of vaporization of ethanol (ethyl alcohol), C2H5OH. C2H5OH(l)C2H5OH(g);H=? The standard enthalpy of formation of C2H5OH(l) is 277.7 kJ/mol and that of C2H5OH(g) is 235.1 kJ/mol.arrow_forwardChloromethane, CH3CI, arises from microbial fermentation and is found throughout the environment. It is also produced industrially, is used in the manufacture of various chemicals, and has been used as a topical anesthetic. How much energy is required to convert 92.5 g of liquid to a vapor at its boiling point, 24.09 C? (The heat of vaporization of CH3Cl is 21.40 kJ/mol.)arrow_forwardBenzene, C6H6, is an organic liquid that freezes at 5.5 C (Figure 11.1) to form beautiful, feather-like crystals. How much energy is evolved as heat when 15.5 g of benzene freezes at 5.5 C? (The enthalpy of fusion of benzene is 9.95 kJ/mol.) If the 15.5-g sample is remelted, again at 5.5 C, what quantity of energy is required to convert it to a liquid?arrow_forward
- Liquid butane, C4H10, is stored in cylinders to be used as a fuel. Suppose 35.5 g of butane gas is removed from a cylinder. How much heat must be provided to vaporize this much gas? The heat of vaporization of butane is 21.3 kJ/mol.arrow_forwardIf you want to convert 56.0 g ice (at 0 °C) to water at 75.0 °C, calculate how many grams of propane, C3H8, you would have to bum to supply the energy to melt the ice and then warm it to the final temperature (at 1 bar).arrow_forwardWhy are steam burns so much worse than water burns even if the H2O is at the same temperature for both phases? Hint: Consider the heat of vaporization of water.arrow_forward
- 1. Which of the following processes requires the largest input of energy as heat? raising the temperature of 100 g of water by 1.0 °C vaporization of 0.10 g of water at 100 °C melting 1.0 g of ice at 0 °C warming 1.0 g of ice from −50 °C to 0 °C (specific heat of ice = 2.06 J/g · K)arrow_forwardWhat quantity of energy does it take to convert 0.500 kg ice at 20.C to steam at 250.C? Specific heat capacities: ice, 2.03 J/g C; liquid, 4.2 J/g . C; steam, 2.0 J/g C; Hvap = 40.7 kJ/mol; Hfus = 6.02 kJ/mol.arrow_forwardCarbon tetrachloride, CCl4, has a vapor pressure of 213 torr at 40.C and 836 torr at 80.C. What is the normal boiling point of CCl4?arrow_forward
- Explain why the enthalpies of vaporization of the following substances increase in the order CH4NH3H2O, even though all three substances have approximately the same molar mass.arrow_forwardSublimation is the phase change from solid to gas without going through a liquid phase. Solid CO2, called dry ice, is an example of one substance that sublimed. Use Hesss law to show that the enthalpy of sublimation, subH, is equal to fusH vapH.arrow_forwardAre changes in state physical or chemical changes? Explain. What type of forces must be overcome to melt or vaporize a substance (are these forces intramolecular or intermolecular)? Define the molar heat of fusion and molar heat of vaporization. Why is the molar heat of vaporization of water so much larger than its molar heat of fusion? Why does the boiling point of a liquid vary with altitude?arrow_forward
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