Chemistry: The Molecular Nature of Matter and Change
Chemistry: The Molecular Nature of Matter and Change
9th Edition
ISBN: 9781260477467
Author: Martin Silberberg
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 11, Problem 11.33P

(a)

Interpretation Introduction

Interpretation:

The orbital designations for the given molecular orbitals are to be determined.

Concept introduction:

The molecular orbital is a mathematical function that describes the wave-like behaviour of an electron in a molecule. The linear combination of atomic orbitals or LCAO is a technique to calculate the number of molecular orbitals that are formed by the combination of atomic orbitals. According to this assumption, n atomic orbitals combine to form n molecular orbitals.

(b)

Interpretation Introduction

Interpretation:

The molecular orbital that is highest in energy is to be determined.

Concept introduction:

The molecular orbital is a mathematical function that describes the wave-like behaviour of an electron in a molecule. The linear combination of atomic orbitals or LCAO is a technique to calculate the number of molecular orbitals that are formed by the combination of atomic orbitals. According to this assumption, n atomic orbitals combine to form n molecular orbitals.

(c)

Interpretation Introduction

Interpretation:

The molecular orbital with the lowest energy is to be determined.

Concept introduction:

The molecular orbital is a mathematical function that describes the wave-like behaviour of an electron in a molecule. The linear combination of atomic orbitals or LCAO is a technique to calculate the number of molecular orbitals that are formed by the combination of atomic orbitals. According to this assumption, n atomic orbitals combine to form n molecular orbitals.

(d)

Interpretation Introduction

Interpretation:

The molecular orbitals are to be ranked in the order of increasing energy for B2.

Concept introduction:

A molecular orbital diagram is a tool that is used to describe the chemical bonding formed between different molecules. It is used to predict the bond strength and the electronic transitions that a molecule can undergo.

The molecular orbital is a mathematical function that describes the wave-like behaviour of an electron in a molecule. The linear combination of atomic orbitals or LCAO is a technique to calculate the number of molecular orbitals that are formed by the combination of atomic orbitals. According to this assumption, n atomic orbitals combine to form n molecular orbitals.

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Chapter 11 Solutions

Chemistry: The Molecular Nature of Matter and Change

Ch. 11 - Prob. 11.3PCh. 11 - Prob. 11.4PCh. 11 - Prob. 11.5PCh. 11 - Give the number and type of hybrid orbital that...Ch. 11 - What is the hybridization of nitrogen in each of...Ch. 11 - What is the hybridization of carbon in each of the...Ch. 11 - Prob. 11.9PCh. 11 - Prob. 11.10PCh. 11 - Prob. 11.11PCh. 11 - Prob. 11.12PCh. 11 - Phosphine (PH3) reacts with borane (BH3) as...Ch. 11 - The illustrations below depict differences in...Ch. 11 - Use partial orbital diagrams to show how the...Ch. 11 - Use partial orbital diagrams to show how the...Ch. 11 - Prob. 11.17PCh. 11 - Prob. 11.18PCh. 11 - Methyl isocyanate, , is an intermediate in the...Ch. 11 - Are these statements true or false? Correct any...Ch. 11 - Prob. 11.21PCh. 11 - Identify the hybrid orbitals used by the central...Ch. 11 - Prob. 11.23PCh. 11 - Identify the hybrid orbitals used by the central...Ch. 11 - Prob. 11.25PCh. 11 - Prob. 11.26PCh. 11 - Certain atomic orbitals on two atoms were combined...Ch. 11 - Prob. 11.28PCh. 11 - Antibonding MOs always have at least one node. Can...Ch. 11 - Prob. 11.30PCh. 11 - Prob. 11.31PCh. 11 - The molecular orbitals depicted are derived from...Ch. 11 - The molecular orbitals depicted below are derived...Ch. 11 - Prob. 11.34PCh. 11 - Use an MO diagram and the bond order you obtain...Ch. 11 - Prob. 11.36PCh. 11 - Prob. 11.37PCh. 11 - Prob. 11.38PCh. 11 - Prob. 11.39PCh. 11 - Epinephrine (or adrenaline; below) is a naturally...Ch. 11 - Prob. 11.41PCh. 11 - Isoniazid (below) is an antibacterial agent that...Ch. 11 - Prob. 11.43PCh. 11 - Prob. 11.44PCh. 11 - Prob. 11.45PCh. 11 - Prob. 11.46PCh. 11 - Tryptophan is one of the amino acids found in...Ch. 11 - Prob. 11.48PCh. 11 - Prob. 11.49PCh. 11 - Prob. 11.50PCh. 11 - Prob. 11.51PCh. 11 - Prob. 11.52PCh. 11 - Sulfur forms oxides, oxoanions, and halides. What...Ch. 11 - Prob. 11.54PCh. 11 - Use an MO diagram to find the bond order and...Ch. 11 - Acetylsalicylic acid (aspirin), the most widely...Ch. 11 - Prob. 11.57P
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