General Chemistry
General Chemistry
7th Edition
ISBN: 9780073402758
Author: Chang, Raymond/ Goldsby
Publisher: McGraw-Hill College
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Concept explainers

Question
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Chapter 11, Problem 11.27QP

(a)

Interpretation Introduction

Interpretation:

The structure of the organic compounds should be given.

Concept introduction:

Organic compounds are named systematically by using IUPAC rules.

Name of the organic compounds are given according to the number of carbon present in the molecule for example

A molecule having one carbon atom, the molecule name will start with meth etc.…

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  1

If any halogens are present in the molecule, the name of the halogens as follows.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  2

Naming the substituted alkane:

  1. (1) Name the parent alkane (long alkyl chain)
  2. (2) Number the carbon
  3. (3) Name and number the substituent

If the molecules have the multiple substituents, the compound named as di, tri, tetra, penta, ect.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  3

If the molecules having functional group, the name of the compound is given below. Numbering should be starts from the functional group of the given molecule.

The given compound is an alcohol (OH), the compound name end up with ol. The name of the compound is given according to the number of carbon atom.

Example is given below

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  4

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  5

The given compound is an acid (COOH), the compound name end up with oic. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  6

The amides are derivatives of acids and it is named as the ending of alkane with amide.

For example

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  7

If the molecule is ester,

Esters end with “ate”

Example

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  8

The given compound is an aldehyde (CHO), the compound name end up with al. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  9

The given compound is an aldehyde (CO), the compound name end up with one. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  10

The given compound is an aldehyde (NH2), the compound name end up with amine. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  11

(a)

Expert Solution
Check Mark

Answer to Problem 11.27QP

  1. (1) Structure of the given organic compounds is shown below

    General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  12

Explanation of Solution

To find: The structure of the given organic molecule.

Name of the given organic compounds is 3-methyl hexane.

  General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  13

Parent chain is identified and numbering is given for the compound. According to the name, third carbon is bearing one methyl group and the given name is hexane which clearly indicates that the compound having six carbon atoms in the molecule. According to the name, the structure of the molecule is given above.

(b)

Interpretation Introduction

Interpretation:

The structure of the organic compounds should be given.

Concept introduction:

Organic compounds are named systematically by using IUPAC rules.

Name of the organic compounds are given according to the number of carbon present in the molecule for example

A molecule having one carbon atom, the molecule name will start with meth etc.…

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  14

If any halogens are present in the molecule, the name of the halogens as follows.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  15

Naming the substituted alkane:

  1. (4) Name the parent alkane (long alkyl chain)
  2. (5) Number the carbon
  3. (6) Name and number the substituent

If the molecules have the multiple substituents, the compound named as di, tri, tetra, penta, ect.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  16

If the molecules having functional group, the name of the compound is given below. Numbering should be starts from the functional group of the given molecule.

The given compound is an alcohol (OH), the compound name end up with ol. The name of the compound is given according to the number of carbon atom.

Example is given below

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  17

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  18

The given compound is an acid (COOH), the compound name end up with oic. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  19

The amides are derivatives of acids and it is named as the ending of alkane with amide.

For example

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  20

If the molecule is ester,

Esters end with “ate”

Example

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  21

The given compound is an aldehyde (CHO), the compound name end up with al. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  22

The given compound is an aldehyde (CO), the compound name end up with one. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  23

The given compound is an aldehyde (NH2), the compound name end up with amine. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  24

(b)

Expert Solution
Check Mark

Answer to Problem 11.27QP

Structure of the given organic compounds is shown below

  General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  25

Explanation of Solution

To find: The structure of the given organic molecule.

Name of the given organic compounds is 1,3,5-trichlorocyclohexane.

  General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  26

Parent chain is identified and numbering is given for the compound. According to the name, the compound is a cyclo compound with six carbon atoms. It bears chlorine at first, third and fifth position.

(c)

Interpretation Introduction

Interpretation:

The structure of the organic compounds should be given.

Concept introduction:

Organic compounds are named systematically by using IUPAC rules.

Name of the organic compounds are given according to the number of carbon present in the molecule for example

A molecule having one carbon atom, the molecule name will start with meth etc.…

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  27

If any halogens are present in the molecule, the name of the halogens as follows.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  28

Naming the substituted alkane:

  1. (7) Name the parent alkane (long alkyl chain)
  2. (8) Number the carbon
  3. (9) Name and number the substituent

If the molecules have the multiple substituents, the compound named as di, tri, tetra, penta, ect.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  29

If the molecules having functional group, the name of the compound is given below. Numbering should be starts from the functional group of the given molecule.

The given compound is an alcohol (OH), the compound name end up with ol. The name of the compound is given according to the number of carbon atom.

Example is given below

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  30

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  31

The given compound is an acid (COOH), the compound name end up with oic. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  32

The amides are derivatives of acids and it is named as the ending of alkane with amide.

For example

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  33

If the molecule is ester,

Esters end with “ate”

Example

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  34

The given compound is an aldehyde (CHO), the compound name end up with al. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  35

The given compound is an aldehyde (CO), the compound name end up with one. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  36

The given compound is an aldehyde (NH2), the compound name end up with amine. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  37

(c)

Expert Solution
Check Mark

Answer to Problem 11.27QP

Structure of the given organic compounds is shown below

  General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  38

Explanation of Solution

To find: The structure of the given organic molecule.

Name of the given organic compounds is 2,3-dimethylpentane

  General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  39

Parent chain is identified and numbering is given for the compound. According to the name, second and third carbon is bearing methyl group and the parent name of the molecule is pentane which clearly indicates that the compound having five carbon atoms in the parent. According to the name, the structure of the molecule is given above.

(d)

Interpretation Introduction

Interpretation:

The structure of the organic compounds should be given.

Concept introduction:

Organic compounds are named systematically by using IUPAC rules.

Name of the organic compounds are given according to the number of carbon present in the molecule for example

A molecule having one carbon atom, the molecule name will start with meth etc.…

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  40

If any halogens are present in the molecule, the name of the halogens as follows.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  41

Naming the substituted alkane:

  1. (10) Name the parent alkane (long alkyl chain)
  2. (11) Number the carbon
  3. (12) Name and number the substituent

If the molecules have the multiple substituents, the compound named as di, tri, tetra, penta, ect.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  42

If the molecules having functional group, the name of the compound is given below. Numbering should be starts from the functional group of the given molecule.

The given compound is an alcohol (OH), the compound name end up with ol. The name of the compound is given according to the number of carbon atom.

Example is given below

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  43

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  44

The given compound is an acid (COOH), the compound name end up with oic. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  45

The amides are derivatives of acids and it is named as the ending of alkane with amide.

For example

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  46

If the molecule is ester,

Esters end with “ate”

Example

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  47

The given compound is an aldehyde (CHO), the compound name end up with al. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  48

The given compound is an aldehyde (CO), the compound name end up with one. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  49

The given compound is an aldehyde (NH2), the compound name end up with amine. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  50

(d)

Expert Solution
Check Mark

Answer to Problem 11.27QP

Structure of the given organic compounds is shown below (c).

  General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  51

Explanation of Solution

To find: The structure of the given organic molecule.

Name of the given organic compounds is 2-bromo-4-phenylpentane.

  General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  52

Parent chain is identified and numbering is given for the compound. According to the name, second carbon is bearing bromine and fourth carbon is bearing phenyl ring and the parent name of the molecule is pentane which clearly indicates that the compound having five carbon atoms in the parent. According to the name, the structure of the molecule is given above.

(e)

Interpretation Introduction

Interpretation:

The structure of the organic compounds should be given.

Concept introduction:

Organic compounds are named systematically by using IUPAC rules.

Name of the organic compounds are given according to the number of carbon present in the molecule for example

A molecule having one carbon atom, the molecule name will start with meth etc.…

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  53

If any halogens are present in the molecule, the name of the halogens as follows.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  54

Naming the substituted alkane:

  1. (13) Name the parent alkane (long alkyl chain)
  2. (14) Number the carbon
  3. (15) Name and number the substituent

If the molecules have the multiple substituents, the compound named as di, tri, tetra, penta, ect.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  55

If the molecules having functional group, the name of the compound is given below. Numbering should be starts from the functional group of the given molecule.

The given compound is an alcohol (OH), the compound name end up with ol. The name of the compound is given according to the number of carbon atom.

Example is given below

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  56

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  57

The given compound is an acid (COOH), the compound name end up with oic. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  58

The amides are derivatives of acids and it is named as the ending of alkane with amide.

For example

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  59

If the molecule is ester,

Esters end with “ate”

Example

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  60

The given compound is an aldehyde (CHO), the compound name end up with al. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  61

The given compound is an aldehyde (CO), the compound name end up with one. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  62

The given compound is an aldehyde (NH2), the compound name end up with amine. The name of the compound is given according to the number of carbon atom.

General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  63

(e)

Expert Solution
Check Mark

Answer to Problem 11.27QP

Structure of the given organic compounds is shown below (d).

  General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  64

Explanation of Solution

To find: The structure of the given organic molecule.

Name of the given organic compounds is 3,4,5-trimethyloctane.

  General Chemistry, Chapter 11, Problem 11.27QP , additional homework tip  65

Parent chain is identified and numbering is given for the compound. According to the name, third, fourth and fifth carbon is bearing methyl group and the parent name of the molecule is octane which clearly indicates that the compound having eight carbon atoms in the parent. According to the name, the structure of the molecule is given above.

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Chapter 11 Solutions

General Chemistry

Ch. 11 - Prob. 11.2QPCh. 11 - Prob. 11.3QPCh. 11 - 11.4 What are structural isomers? Ch. 11 - Prob. 11.5QPCh. 11 - 11.6 Draw skeletal structures of the boat and...Ch. 11 - 11.7 Alkenes exhibit geometric isomerism because...Ch. 11 - 11.8 Why is it that alkanes and alkynes, unlike...Ch. 11 - Prob. 11.9QPCh. 11 - 11.10 Describe reactions that are characteristic...Ch. 11 - Prob. 11.11QPCh. 11 - Prob. 11.12QPCh. 11 - Prob. 11.13QPCh. 11 - Prob. 11.14QPCh. 11 - Prob. 11.15QPCh. 11 - Prob. 11.16QPCh. 11 - Prob. 11.17QPCh. 11 - 11.18 Draw Newman projections of four different...Ch. 11 - 11.19 Draw the structures of cis-2-butene and...Ch. 11 - 11.20 Would you expect cyclobutadiene to be a...Ch. 11 - Prob. 11.21QPCh. 11 - Prob. 11.22QPCh. 11 - 11.23 Sulfuric acid (H2SO4) adds to the double...Ch. 11 - Prob. 11.24QPCh. 11 - Prob. 11.25QPCh. 11 - Prob. 11.26QPCh. 11 - Prob. 11.27QPCh. 11 - Prob. 11.28QPCh. 11 - Prob. 11.29QPCh. 11 - 11.30 Benzene and cyclohexane both contain...Ch. 11 - Prob. 11.31QPCh. 11 - Prob. 11.32QPCh. 11 - Prob. 11.33QPCh. 11 - Prob. 11.34QPCh. 11 - Prob. 11.35QPCh. 11 - Prob. 11.36QPCh. 11 - Prob. 11.37QPCh. 11 - Prob. 11.38QPCh. 11 - Prob. 11.39QPCh. 11 - Prob. 11.40QPCh. 11 - Prob. 11.41QPCh. 11 - Prob. 11.42QPCh. 11 - Prob. 11.43QPCh. 11 - Prob. 11.44QPCh. 11 - Prob. 11.45QPCh. 11 - Prob. 11.46QPCh. 11 - Prob. 11.47QPCh. 11 - Prob. 11.48QPCh. 11 - Prob. 11.49QPCh. 11 - Prob. 11.50QPCh. 11 - Prob. 11.51QPCh. 11 - Prob. 11.52QPCh. 11 - Prob. 11.53QPCh. 11 - Prob. 11.54QPCh. 11 - Prob. 11.55QPCh. 11 - Prob. 11.56QPCh. 11 - Prob. 11.57QPCh. 11 - Prob. 11.58QPCh. 11 - Prob. 11.59QPCh. 11 - Prob. 11.60QPCh. 11 - Prob. 11.61QPCh. 11 - Prob. 11.62QPCh. 11 - Prob. 11.63QPCh. 11 - Prob. 11.64QPCh. 11 - Prob. 11.65QPCh. 11 - Prob. 11.66QPCh. 11 - Prob. 11.67QPCh. 11 - Prob. 11.68QPCh. 11 - Prob. 11.69QPCh. 11 - Prob. 11.70QPCh. 11 - Prob. 11.71QPCh. 11 - Prob. 11.72QPCh. 11 - 11.73 Octane number is assigned to gasoline to...Ch. 11 - Prob. 11.74SPCh. 11 - Prob. 11.75SPCh. 11 - Prob. 11.76SPCh. 11 - Prob. 11.77SPCh. 11 - Prob. 11.78SP
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