The major product should be given, if NH 3 shift occurs. Concept introduction: Aromaticity: The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are, The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Answer 1

Question

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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4. Which of the following reactions is NOT a method of preparation of alkylhalide? A. addition of halogens to alkenes B. replacement of the -OH in alcohol by a halide C. dehydrohalogenation of hydrocarbon D. addition of hydrogen halide to alkene 5. In SN₂ reaction of alkylhalide(substrate) with NaOH(nucleophile), the rate of the reaction is tripled if the concentration of: A. Substrate and nucleophile are both doubled B. Nucleophile is decreased by 1/3 and substrate doubled C. Substrate is tripled and nucleophile doubled D. Nucleophile is tripled 6. Arrange the following alkylhalide in order of decreasing reactivity in an SN₁ reaction: I. CH3CH(Br)CH₂CH3 A. I>II>III>IV II. CH3CH(C1)CH₂CH3 III. CICH₂CH₂CH₂CH3 IV. (CH3)2C(Br)CHCH3 D. IV>II>I>III B. IV>III>II>I C. IV>I>II>III

The existence of the NIH shift was established by determining the major product obtained from rearrangement of the following arene oxide, in which a hydrogen has been replaced by a deuterium. a. What would be the major product if the NIH shift occurs? b. What would be the major product if the carbocation forms phenol by losing H+ or D+, rather than by going through the NIH shift?

The existence of the NIH shift was established by determining the major product obtained from rearrangement of the following arene oxide, in which a hydrogen has been replaced by a deuterium. a. What would be the major product if the NIH shift occurs? (Hint: A C¬H bond is easier to break than a C¬D bond.)b. What would be the major product if the carbocation forms phenol by losing H+ or D+, rather than by going through the NIH shift?

Answer 2

Question

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Answer 3

Question

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Answer 4

Question

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Answer 5

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 6

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 7

Chapter 10.8, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 10.1 - Why are NH3 and CH3NH2 no longer nucleophiles when...Ch. 10.1 - Explain the difference in reactivity between...Ch. 10.1 - Prob. 5P Ch. 10.1 - Prob. 6P Ch. 10.1 - Prob. 8P Ch. 10.2 - Prob. 9P Ch. 10.3 - Prob. 11P Ch. 10.3 - Show how 1-propanol can be converted into the...Ch. 10.4 - Which of the following alcohols dehydrates the...Ch. 10.4 - Prob. 14P

Solution Summary: The author explains that aromatic compounds are type of organic compounds, which has a special property's in the reactivity and structure.

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