E2 elimination products of (2S,3S)-2-chloro-3-methylpentane drawn. Concept Introduction: An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step. A strong base favours an E2 reaction. A high concentration of a base favours an E2 reaction. If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

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Answer 1

Question

Chapter 10, Problem 53P

(a)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(b)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(c)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(d)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(e)

Interpretation Introduction

Interpretation:

E2 elimination products of 3-chloro-3-ethyl-2,2-dimethylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

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115. Draw the products of each of the following S,2/E2 reactions. If the products can exist as stereoisomers, show which stereoisomers are formed. a. (3S,4S)-3-bromo-4-methylhexane + CH;O b. (3R,4R)-3-bromo-4-methylhexane + CH30 c. (3S,4R)-3-bromo-4-methylhexane + CH;O¯ d. (3R,4S)-3-bromo-4-methylhexane + CH3O

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Answer 2

Question

Chapter 10, Problem 53P

(a)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(b)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(c)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(d)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(e)

Interpretation Introduction

Interpretation:

E2 elimination products of 3-chloro-3-ethyl-2,2-dimethylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

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Answer 3

Question

Chapter 10, Problem 53P

(a)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(b)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(c)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(d)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(e)

Interpretation Introduction

Interpretation:

E2 elimination products of 3-chloro-3-ethyl-2,2-dimethylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

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Answer 4

Question

Chapter 10, Problem 53P

(a)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(b)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(c)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(d)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(e)

Interpretation Introduction

Interpretation:

E2 elimination products of 3-chloro-3-ethyl-2,2-dimethylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

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Answer 5

Chapter 10, Problem 53P

(a)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(b)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(c)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(d)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

(e)

Interpretation Introduction

Interpretation:

E2 elimination products of 3-chloro-3-ethyl-2,2-dimethylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

Answer 6

Chapter 10, Problem 53P

(a)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

Answer 7

Chapter 10, Problem 53P

(a)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

Answer 8

(b)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

Answer 9

(b)

Interpretation Introduction

Interpretation:

E2 elimination products of (2S,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

Answer 10

(c)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

Answer 11

(c)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3S)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

Answer 12

(d)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

Answer 13

(d)

Interpretation Introduction

Interpretation:

E2 elimination products of (2R,3R)-2-chloro-3-methylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

Answer 14

(e)

Interpretation Introduction

Interpretation:

E2 elimination products of 3-chloro-3-ethyl-2,2-dimethylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

Answer 15

(e)

Interpretation Introduction

Interpretation:

E2 elimination products of 3-chloro-3-ethyl-2,2-dimethylpentane drawn.

Concept Introduction:

An E2 reaction is a concerted, one-step reaction in which the proton and the halide ion are removed in the same step.

A strong base favours an E2 reaction.

A high concentration of a base favours an E2 reaction.

If one of the reactants is charged, an E2 reaction will be favoured by the least polar solvent that will dissolve the reactant. If neither of the reactant is charged an E2 reaction is favoured by the protic polar solvent.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 10.2 - Prob. 1P Ch. 10.2 - Prob. 2P Ch. 10.2 - Prob. 3P Ch. 10.2 - Prob. 4P Ch. 10.3 - Four alkenes are formed from the E1 reaction of...Ch. 10.3 - If 2-fluoropentane could undergo an E1 reaction,...Ch. 10.3 - Prob. 7P Ch. 10.3 - Propose a mechanism for the following reaction:Ch. 10.4 - Prob. 9P Ch. 10.4 - What products will be obtained from the El...

Solution Summary: The author explains that an E2 reaction is a concerted one-step reaction in which the proton and the halide ion are removed in the same step.

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