Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Textbook Question
Chapter 10, Problem 43P
Starting with an
- a. 2-methoxybutane
- b. 1-methoxybutane
- c. butylmethylamine
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Show how to convert cyclohexanol to these compounds.
a. Cyclohexene
b. Cyclohexane
c. Cyclohexanone
d. Bromocyclohexane
1. An alkene reacts with water with an acid catalyst results into a formation of:
A. Aldehyde
B. Ketone
C. Alcohol
D. Ester
2. 3-Methylhexanal with K2Cr2O7 will yield:
A. 3-Methyl-1-hexanol
B. 3-Methylhexanoic acid
C. 3-Methyl-1-hexanone
D. 3-Methyl-1-hexanethiol
3. This is a reverse process of Hydration reaction:
A. Oxidation reaction
B. Reduction reaction
C. Dehydration reaction
D. Hydration reaction
4. Acetic acid reacts with a strong base forms:
A. Salt
B. Water
C. Salt and Water
D. No reaction
5. Ketones can be further oxidized with benedict's solution into:
A. Alcohol
B. Aldehyde
C. Catalysts
D. No reaction
Cyclopentanone is treated with chlorine (Cl2) in the presence of acid (H*).
What product is formed?
A. Chlorocyclopentane
B. 1-chloro-1-hydroxycyclopentane
C. 2-chlorocyclopentanone
D. 3-chlorocyclopentanone
Chapter 10 Solutions
Organic Chemistry
Ch. 10.2 - Prob. 1PCh. 10.2 - Prob. 2PCh. 10.2 - Prob. 3PCh. 10.2 - Prob. 4PCh. 10.3 - Four alkenes are formed from the E1 reaction of...Ch. 10.3 - If 2-fluoropentane could undergo an E1 reaction,...Ch. 10.3 - Prob. 7PCh. 10.3 - Propose a mechanism for the following reaction:Ch. 10.4 - Prob. 9PCh. 10.4 - What products will be obtained from the El...
Ch. 10.4 - Prob. 11PCh. 10.5 - Prob. 12PCh. 10.6 - Prob. 14PCh. 10.7 - Why do cis-1-bromo-2-ethylcyclohexane and...Ch. 10.7 - Which isomer reacts more rapidly in an E2...Ch. 10.7 - Prob. 18PCh. 10.8 - Prob. 19PCh. 10.8 - Prob. 20PCh. 10.9 - Prob. 21PCh. 10.9 - Explain why only a substitution product and no...Ch. 10.9 - Prob. 23PCh. 10.9 - Prob. 24PCh. 10.9 - Prob. 25PCh. 10.9 - a. Explain why 1-bromo-2,2-dimethylpropane has...Ch. 10.10 - A small amount of another organic product is...Ch. 10.10 - What is the best way to prepare the following...Ch. 10.10 - Prob. 29PCh. 10.10 - Prob. 30PCh. 10.10 - Why is a cumulated diene not formed in the...Ch. 10.10 - What product is obtained when the following...Ch. 10.11 - Prob. 33PCh. 10.11 - Prob. 34PCh. 10 - Draw the major product obtained when each of the...Ch. 10 - Prob. 36PCh. 10 - a. Indicate how each of the following factors...Ch. 10 - Prob. 38PCh. 10 - A chemist wanted to synthesize the...Ch. 10 - Prob. 40PCh. 10 - Prob. 41PCh. 10 - Prob. 42PCh. 10 - Starting with an alkyl halide, how could the...Ch. 10 - Indicate which species in each pair gives a higher...Ch. 10 - Prob. 45PCh. 10 - For each of the following alkyl halides, indicate...Ch. 10 - Prob. 47PCh. 10 - When 2-bromo-2,3-dimethylbutane reacts with a...Ch. 10 - Prob. 49PCh. 10 - When the following compound undergoes solvolysis...Ch. 10 - cis-1-Bromo-4-tert-butylcyclohexane and...Ch. 10 - Draw the substitution and elimination products.Ch. 10 - Prob. 53PCh. 10 - Prob. 54PCh. 10 - Which of the following hexachlorocyclohexanes is...Ch. 10 - Explain why the rate of the reaction of...Ch. 10 - Prob. 57PCh. 10 - Two elimination products are obtained from the...Ch. 10 - Draw the structures or the product of the obtained...Ch. 10 - How could you prepare the following compounds from...Ch. 10 - cis-4-Bromocyclohexanol and...Ch. 10 - Prob. 62PCh. 10 - Prob. 63P
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- Determine the product of the reaction considering the conditions given. A. No product will be formed B. 2-methoxy-2,3,3-trimethylpentane C. 2,3,3-trimethyl-1-pentanearrow_forwardон C-H ÓR Compound that contains a group like that shown above. a. acetal Ob. aldehyde c. Benedict's reagent d. carbonyl Oe. hemiacetal Of. hemiketal Og. hydrolysis h. ketal i. ketone Oj. Tollen's reagent 2.arrow_forwardWhat is the name for this compound? Select one: a. 2-bromo-5-ethylphenol b. 4-bromo-1-ethyl-5-phenol c. 6-bromo-3-ethylphenol d. 2-bromo-5-ethylcyclohexanol e. 2-bromo-5-methylphenolarrow_forward
- 4- Choose the correct reactants required to synthesize the following molecule. H3CO OCH 3 A. Acetone and methanal B. Acetone and methanol C. Formaldehyde and propanal D. Formaldehyde and propanol 5- What is the IUPAC name of the following compound? CI A. 6-Chloro-4-ethoxy-1-octanal B. 6-Chloro-4-ethoxyoctanal C. 6-Chloro-4-ethoxycyclooctanal D. 4-Ethoxy-6-chlorooctanal - What is the IUPAC name of the following compound? 0 Br. Br Cl A. 2,6-Dibromo-3-chloro-5,5-dimethylhexanone B. 2,6-Dibromo-3-chloro-5,5-dimethylcyclohexanone C. 2,6-Dibromo-5-chloro-3,3-dimethylhexanone D. 2,6-Dibromo-5-chloro-3,3-dimethylcyclohexanonearrow_forward1. Which carbonyl group of the given compound is most reactive for nucleophilic addition reaction? a. All have equal reactivity b. Carbonyl Group 1 c. Carbonyl Group 2 d. Carbonyl Group 2. An aldehyde commonly exhibits a nucleophilic addition type of reaction. When a nucleophile attacks a carbonyl carbon, what happens to the oxygen atom in the structure? Refer to the structure below. ~ a. Oxygen atom becomes more electronegative. b. Oxygen atom obtains a net negative charge. c. Oxygen atom transforms to an alkoxide group. d. Oxygen atom acts as the new electrophile. 3. Assign the trivial name of the structure below. a. Diphenylketone b. Benzyl phenylketone c. Diphenyl aldehyde d. Benzyl phenyl aldehydearrow_forwardHow would you convert the following compounds into butanoic acid using reagents from the table? a. 4-octene b. 1-butenearrow_forward
- What product(s) will form: 2-Pentene + H₂O → O a. 2-Pentanol O b. Isopropyl alcohol O c. 3-Pentanol O d. a 50/50 mixture of 2-Pentanol and 3-Pentanol Oe. no reaction will occurarrow_forwardAlkyl halide can be prepared from the addition of H-X to alkenes. Identify the product in the reaction. H-Br Select one: a. 1,2-dibromo-2-methylpropane b. 1-bromo-2-methylpropane c. t-butyl bromide (or 2-bromo-2-methylpropane) d. 2-methylpropanearrow_forwardShow how to prepare each compound from 2-methyl- 1- propanol. a. 2- methylpropene b. 2- methyl- 2- propanol c. 2- methylpropanoic acid (CH3)2CHCOOHarrow_forward
- Draw structural formulas for the alkene that gives each alcohol upon hydroborationoxidation. OH HO, b. a.arrow_forward5. What is the IUPAC name for the following compound? a. 4-hexanone b. 3-hexanone c. ethyl propyl ketone d. propyl ethyl ketone 6. What is the IUPAC name for the following compound? HO OH a. 2,3-dihydroxycyclopentanone b. 1,2-dihydroxy-3-cyclopentanone c. cyclopentanone-1,2-diol 7. What is the correct order of boiling points for the following compounds? ean d. cyclopentanone-2,3-diol HO. A B a. A>B>C b. C>B>A с. В> A>С d. A>C>B 8. Which of the following has the highest water solubility? a. butanal ь. 1-butanol c. I-hexanol d. hexanal 9. Which of the following is true of ketones? a. Most ketones are odorless. b. Most ketones have mild odors. c. Most ketones have strong pleasant odors. d. Most ketones have strong unpleasant odors. JPW Te orheries 10. Which of the following statements is true? a. Both aldehydes and ketones are easily oxidized. b. Neither aldehydes nor ketones are easily oxidized. c. Aldehydes are easily oxidized, but ketones are not. d. Ketones are easily oxidized, but…arrow_forward2-Methyl-2-butene reacts with HBr in the presence of peroxide to give a. a secondary alkyl bromide. b. a primary alkyl bromide. c. a tertiary alkyl bromide. d. a vicinal dibromide.arrow_forward
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