General Chemistry: Principles and Modern Applications (11th Edition)
General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
bartleby

Concept explainers

Question
Book Icon
Chapter 10, Problem 117IAE
Interpretation Introduction

(a)

Interpretation:

The percent ionic character for LiBr and NaCl bonds separately needs to be determined.

Concept introduction:

Several empirical equations have been proposed to calculate the percentage ionic character in the bond. It is important to note that no bond (even ionic) in chemistry is 100% ionic.

In a bond, the dipole moment can be calculated as follows:

µ = δ×d

Here,

µ = Dipole mment

δ = Partial charge

d = Distance

Interpretation Introduction

(b)

Interpretation:

The calculated ionic characters of LiBr and NaCl needs to be compared with given theoretical values of figure based on electronegativity values.

Concept introduction:

Several empirical equations have been proposed to calculate the percentage ionic character in the bond. It is important to note that no bond (even ionic) in chemistry is 100% ionic.

In a bond, the dipole moment can be calculated as follows:

µ = δ×d

Here,

µ = Dipole mment

δ = Partial charge

d = Distance

Interpretation Introduction

(c)

Interpretation:

The reason for equality of calculated percentage ionic values and given data based on electronegativity needs to be explained.

Concept introduction:

Several empirical equations have been proposed to calculate the percentage ionic character in the bond. It is important to note that no bond (even ionic) in chemistry is 100% ionic.

In a bond, the dipole moment can be calculated as follows:

µ = δ×d

Here,

µ = Dipole mment

δ = Partial charge

d = Distance

Blurred answer
Students have asked these similar questions
Two substances with empirical formula HNO are hyponi-trous acid ( μ=62.04 g /mol) and nitroxyl (μ=31.02 g/mol).(a) What is the molecular formula of each species?(b) For each species, draw the Lewis structure having the lowestformal charges. (Hint:Hyponitrous acid has an N=N bond.)(c) Predict the shape around the N atoms of each species.(d) When hyponitrous acid loses two protons, it forms the hy-ponitrite ion. Draw cisand transforms of this ion.
iv. Assign formal charges to the atoms in the following structures and decide which the more important contributor to the resonance hybrid is. (a) (b) H H C=N=N c-N=N H H v. What factor accounts for each of the following differences in bond length? (a) I, has a longer bond than Br,. (b) C-N bonds are shorter than C-C bonds. (c) H-C bonds are shorter than the C-O bond. (d) The C-O bond in formaldehyde, H,C=0, is longer than the bond in carbon monoxide, C=0.
Arrange the following in the order of the property indicated for each set–(a) F2, Cl2, Br2, I2(Increasing bond dissociation energy).(b) HF, HCl, HBr, HI (decreasing acid strength).(c) NH3, PH3, ASH3, SbH3, BiH3(decreasing base strength).

Chapter 10 Solutions

General Chemistry: Principles and Modern Applications (11th Edition)

Ch. 10 - Prob. 11ECh. 10 - Indicate what is wrong with each of the following...Ch. 10 - Write Lewis structures for the following ionic...Ch. 10 - Under appropriate conditions, both hydrogen and...Ch. 10 - Derive the correct formulas for the following...Ch. 10 - Each of the following ionic compounds consists of...Ch. 10 - Assign formal charges to each of the atoms in the...Ch. 10 - Assign formal charges to each of the atoms in the...Ch. 10 - Both oxidation state and formal charge involve...Ch. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - Assign formal charges to the atoms in the...Ch. 10 - Prob. 23ECh. 10 - Show that the idea of minimizing the formal...Ch. 10 - Write acceptable Lewis structures for the...Ch. 10 - Two molecules that have the same formulas but...Ch. 10 - The following polyatomic anions involve covalent...Ch. 10 - Represent the following ionic compounds by Lewis...Ch. 10 - Write a plausible Lewis structure for...Ch. 10 - Prob. 30ECh. 10 - Write Lewis structures for the molecules...Ch. 10 - Write Lewis structures for the molecules...Ch. 10 - Write Lewis structures for the molecules...Ch. 10 - Write Lewis structures for the molecules...Ch. 10 - Identify the main group that the element X belongs...Ch. 10 - Prob. 36ECh. 10 - Use your knowledge of electronegativities, but do...Ch. 10 - Which of the blowing molecules would you expect to...Ch. 10 - What is the percent ionic character of each of the...Ch. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Use a cross-base arrow () to represent the...Ch. 10 - Which electrostatic potential map corresponds to...Ch. 10 - Prob. 44ECh. 10 - Two electrostatic potential maps are shown, one...Ch. 10 - Prob. 46ECh. 10 - Prob. 47ECh. 10 - Which of the following species requires a...Ch. 10 - Dinitrogen oxide (nitrous oxide, or "laughing...Ch. 10 - The Lewis structure of nitric acid, HONO2, is a...Ch. 10 - Draw Lewis structures for the following species,...Ch. 10 - Draw Lewis structures for the following species,...Ch. 10 - Write plausible Lewis structures for the following...Ch. 10 - Write plausible Lewis structures for the following...Ch. 10 - Which of the following species would you expect to...Ch. 10 - Write a plausible Lewis structure for NO2 , and...Ch. 10 - In which of the following species is it necessary...Ch. 10 - Prob. 58ECh. 10 - Use VSEPR theory to predict the geometric shapes...Ch. 10 - Use VSEPR theory to predict the geometric shapes...Ch. 10 - Each of the following is either linear, angular...Ch. 10 - Predict the geometric shapes of (a) CO ; (b)...Ch. 10 - One of the following ions has a trigonal-planer...Ch. 10 - Two of the following have the same shape. Which...Ch. 10 - Prob. 65ECh. 10 - Sketch the probable geometric shape of molecule of...Ch. 10 - Use the VSEPR theory to predict the shapes of the...Ch. 10 - Use the VSEPR theory to predict the shape of (a)...Ch. 10 - The molecular shape of BF2 is planar (see Table...Ch. 10 - Explain why it is not necessary to find the Lewis...Ch. 10 - Comment on the similarities and differences in the...Ch. 10 - Comment on the similarities and differences in the...Ch. 10 - Draw a plausible Lewis structure for the following...Ch. 10 - Draw a plausible Lewis structure for the following...Ch. 10 - Sketch the propyne molecule, CH2CCH. Indicate the...Ch. 10 - Sketch the propene molecule, CH2CHCH2. Indicate...Ch. 10 - Lactic acid has the formula CH2CH(OH)COOH. Sketch...Ch. 10 - Levulinic acid has the formula CH2(CO)CH2CH2COOH....Ch. 10 - Prob. 79ECh. 10 - Prob. 80ECh. 10 - Predict the shapes of the following molecules, and...Ch. 10 - Which of the blowing molecules would you expect to...Ch. 10 - The molecule H2O2 has a resultant dipole moment of...Ch. 10 - Prob. 84ECh. 10 - Without referring to tables in the text, indicate...Ch. 10 - Estimate the lengths of the blowing bonds and...Ch. 10 - A relationship between bond lengths and...Ch. 10 - In which of the following molecules would you...Ch. 10 - Prob. 89ECh. 10 - Prob. 90ECh. 10 - A reaction involved in the formation of ozone the...Ch. 10 - Use data from Table 10.3, but without performing...Ch. 10 - Use data from Table 10.3 to estimate the enthalpy...Ch. 10 - One of the chemical reactions that occurs in the...Ch. 10 - Estimate the standard enthalpies of formation at...Ch. 10 - Prob. 96ECh. 10 - Use bond energies from Table 10.3 to estimate rH...Ch. 10 - Equations (1) end (2) can be combined to yield the...Ch. 10 - One reaction involved in the sequence of reactions...Ch. 10 - Prob. 100ECh. 10 - Given the bond-dissociation energies:...Ch. 10 - Prob. 102IAECh. 10 - Prob. 103IAECh. 10 - Prob. 104IAECh. 10 - Prob. 105IAECh. 10 - Draw Lewis structures for two different molecules...Ch. 10 - Sodium azide, NaN2 is the nitrogen gas-forming...Ch. 10 - Prob. 108IAECh. 10 - Prob. 109IAECh. 10 - A few years ago the synthesis of a salt containing...Ch. 10 - Prob. 111IAECh. 10 - In certain polar solvents, PCI, undergoes an...Ch. 10 - Prob. 113IAECh. 10 - Prob. 114IAECh. 10 - Use the VSEPR theory to predict a probable shape...Ch. 10 - The standard enthalpy of formation of...Ch. 10 - Prob. 117IAECh. 10 - Prob. 118IAECh. 10 - Prob. 119IAECh. 10 - R. S. Mulliken proposed that the electronegativity...Ch. 10 - When molten sulfur reacts with chlorine gas, a...Ch. 10 - Hydrogen azide, HN2 , can exist in two forms. One...Ch. 10 - Prob. 123IAECh. 10 - Prob. 124IAECh. 10 - Prob. 125IAECh. 10 - One of the allotropes of sulfur is a ring of eight...Ch. 10 - One of the allotropes of phosphorus consists of...Ch. 10 - In this problem, we examine the basis of three...Ch. 10 - Prob. 129FPCh. 10 - Prob. 130FPCh. 10 - Prob. 131SAECh. 10 - Briefly describe each of the following ideas: (a)...Ch. 10 - Explain the important distinctions between (a)...Ch. 10 - Prob. 134SAECh. 10 - The formal charges on the O atoms in the ion...Ch. 10 - Which molecule is nonlinear?...Ch. 10 - Which molecule is nonpolar?...Ch. 10 - The highest bond-dissociation energy is found in...Ch. 10 - The greatest bond length is found in...Ch. 10 - Draw plausible Lewis structures for the blowing...Ch. 10 - Predict the shapes of the following...Ch. 10 - Which of the following ionic compounds is composed...Ch. 10 - Which of the following molecules does not obey the...Ch. 10 - Which of the following molecules has no polar...Ch. 10 - The electron-group geometry of H2O is (a)...Ch. 10 - For each of the following compounds, give the...Ch. 10 - Use bond enthalpies from Table 10.3 to determine...Ch. 10 - Prob. 148SAECh. 10 - Prob. 149SAECh. 10 - What is the VSEPR theory? On what physical basis...Ch. 10 - Prob. 151SAECh. 10 - Prob. 152SAECh. 10 - Prob. 153SAECh. 10 - Prob. 154SAE
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Text book image
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning