Chemical Principles: The Quest for Insight
Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
Question
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Chapter 10, Problem 10C.5E

(a)

Interpretation Introduction

Interpretation:

The amount of energy released has to be given.

Concept Introduction:

Nuclear binding energy and the mass defect:

Nuclear binding energy is the minimum energy that would be required to disassemble the nucleus of an atom into its component parts.  These component parts are neutrons and protons which are collectively called nucleons.  The mass of an atomic nucleus is less than the sum of the individual masses of the free constituent protons and neutrons according to Einstein’s equation E=mc2.  The missing mass is known as the mass defect and represents the energy that was released when the nucleus was formed.

  Δm=mass of the products -mass of the reactants

(a)

Expert Solution
Check Mark

Answer to Problem 10C.5E

The total amount energy released is E=0.142×1012J.

Explanation of Solution

Given:

The mass of neutron is 1.008664u.

The mass of Deuterium is 2.0141mu.

The mass of the Helium-3 is 3.0160mu.

The mass defect can be calculated as,

  Δm=mass of the products -mass of the reactants

Mass of the reactants =4.024mu.

Mass of the products =4.0282mu.

  Δm=-0.0042×1.66054×10-27=0.0069×10-27kg

The change in energy (ΔE) =Δm×c2

  (ΔE)=0.0069×10-27×(3×108ms-1)2

  (ΔE)=0.0621×10-11J.

The number of atoms in the sample is,

  N=massofthesamplemassoftheatomN=1.00×10-3kg2.0141×1.66054×10-27kgN=2.2899×1023

The total amount of energy released is,

  E=NΔEE=2.2899×1023(0.0621×10-11)E=0.142×1012J

The total amount energy released is E=0.142×1012J.

(b)

Interpretation Introduction

Interpretation:

The amount of energy released has to be given.

Concept Introduction:

Refer to part (a).

(b)

Expert Solution
Check Mark

Answer to Problem 10C.5E

The total amount energy released is E=5.87×1010J.

Explanation of Solution

Given:

The mass of Hydrogen-1 is 1.0078u.

The mass of Deuterium is 2.0141mu.

The mass of the Helium-3 is 3.0160mu.

The mass of Helium-4 is 4.0026mu.

The mass defect can be calculated as,

  Δm=mass of the products -mass of the reactants

  Δm=-0.0197×1.66054×10-27=3.271×10-30kg

The change in energy (ΔE) =Δm×c2

  (ΔE)=3.271×10-30×(3×108ms-1)2

  (ΔE)=2.944×10-13J.

The number of atoms in the sample is,

  N=massofthesamplemassoftheatomN=1.00×10-3kg3.0160×1.66054×10-27kgN=1.9967×1023

The total amount of energy released is,

  E=NΔEE=1.9967×1023(2.944×10-13J)E=5.87×1010J

The total amount energy released is E=5.87×1010J.

(c)

Interpretation Introduction

Interpretation:

The amount of energy released has to be given.

Concept Introduction:

Refer to part (a).

(c)

Expert Solution
Check Mark

Answer to Problem 10C.5E

The total amount energy released is E=2.39×1012J.

Explanation of Solution

Given:

The mass of Hydrogen-1 is 1.0078u.

The mass of Lithium is 7.0160mu.

The mass of Helium-4 is 4.0026mu.

The mass defect can be calculated as,

  Δm=mass of the products -mass of the reactants

  Δm=-0.0187×1.66054×10-27=0.03105×10-27kg

The change in energy (ΔE) =Δm×c2

  (ΔE)=0.03105×10-27×(3×108ms-1)2

  (ΔE)=2.794×10-11J.

The number of atoms in the sample is,

  N=massofthesamplemassoftheatomN=1.00×10-3kg7.0160×1.66054×10-27kgN=8.58×1023

The total amount of energy released is,

  E=NΔEE=8.58×1023(2.794×10-11J)E=2.39×1012J

The total amount energy released is E=2.39×1012J.

(d)

Interpretation Introduction

Interpretation:

The total amount of energy released has to be given.

Concept Introduction:

Refer to part (a).

(d)

Expert Solution
Check Mark

Answer to Problem 10C.5E

The total amount energy released is E=6.44×1012J.

Explanation of Solution

Given:

The mass of neutron is 1.008664u.

The mass of Deuterium is 2.0141mu.

The mass of Helium-4 is 4.0026mu.

The mass of tritium is 3.0160mu.

The mass defect can be calculated as,

  Δm=mass of the products -mass of the reactants

  Δm=-0.01884×1.66054×10-27=0.03128×10-27kg

The change in energy (ΔE) =Δm×c2

  (ΔE)=0.03128×10-27×(3×108ms-1)2

  (ΔE)=2.815×10-11J.

The number of atoms in the sample is,

  N=massofthesamplemassoftheatomN=1.00×10-3kg2.0141×1.66054×10-27kgN=2.2899×1023

The total amount of energy released is,

  E=NΔEE=2.2899×1023(2.815×10-11J)E=6.44×1012J

The total amount energy released is E=6.44×1012J.

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Chapter 10 Solutions

Chemical Principles: The Quest for Insight

Ch. 10 - Prob. 10A.5ECh. 10 - Prob. 10A.6ECh. 10 - Prob. 10A.7ECh. 10 - Prob. 10A.8ECh. 10 - Prob. 10A.9ECh. 10 - Prob. 10A.10ECh. 10 - Prob. 10A.11ECh. 10 - Prob. 10A.12ECh. 10 - Prob. 10A.13ECh. 10 - Prob. 10A.14ECh. 10 - Prob. 10A.15ECh. 10 - Prob. 10A.16ECh. 10 - Prob. 10A.17ECh. 10 - Prob. 10A.18ECh. 10 - Prob. 10A.19ECh. 10 - Prob. 10A.20ECh. 10 - Prob. 10A.21ECh. 10 - Prob. 10A.22ECh. 10 - Prob. 10A.23ECh. 10 - Prob. 10A.24ECh. 10 - Prob. 10A.25ECh. 10 - Prob. 10A.26ECh. 10 - Prob. 10B.1ASTCh. 10 - Prob. 10B.1BSTCh. 10 - Prob. 10B.2ASTCh. 10 - Prob. 10B.2BSTCh. 10 - Prob. 10B.1ECh. 10 - Prob. 10B.2ECh. 10 - Prob. 10B.3ECh. 10 - Prob. 10B.4ECh. 10 - Prob. 10B.5ECh. 10 - Prob. 10B.6ECh. 10 - Prob. 10B.7ECh. 10 - Prob. 10B.8ECh. 10 - Prob. 10B.9ECh. 10 - Prob. 10B.10ECh. 10 - Prob. 10B.11ECh. 10 - Prob. 10B.12ECh. 10 - Prob. 10B.13ECh. 10 - Prob. 10B.17ECh. 10 - Prob. 10B.18ECh. 10 - Prob. 10B.19ECh. 10 - Prob. 10C.1ASTCh. 10 - Prob. 10C.1BSTCh. 10 - Prob. 10C.2ASTCh. 10 - Prob. 10C.2BSTCh. 10 - Prob. 10C.1ECh. 10 - Prob. 10C.2ECh. 10 - Prob. 10C.3ECh. 10 - Prob. 10C.4ECh. 10 - Prob. 10C.5ECh. 10 - Prob. 10C.6ECh. 10 - Prob. 10C.7ECh. 10 - Prob. 10C.8ECh. 10 - Prob. 10C.9ECh. 10 - Prob. 10C.10ECh. 10 - Prob. 10.1ECh. 10 - Prob. 10.2ECh. 10 - Prob. 10.3ECh. 10 - Prob. 10.4ECh. 10 - Prob. 10.6ECh. 10 - Prob. 10.8ECh. 10 - Prob. 10.9ECh. 10 - Prob. 10.10ECh. 10 - Prob. 10.12ECh. 10 - Prob. 10.15ECh. 10 - Prob. 10.17ECh. 10 - Prob. 10.19ECh. 10 - Prob. 10.20ECh. 10 - Prob. 10.21E
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