EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 9780321787989
Author: KARTY
Publisher: PEARSON CO
expand_more
expand_more
format_list_bulleted
Question
Chapter 10, Problem 10.68P
Interpretation Introduction
Interpretation:
It is to be explained why the E2 mechanism does not occur readily under the given condition.
Concept introduction:
Epoxide is a three membered ring involving an oxygen and two carbon atoms. The ring is highly strained. The small ring size forces the groups on the adjacent atoms to be 1200 away, that is, the dihedral angle between the oxygen atom and the hydrogen atom of the adjacent carbon is 1200. For the E2 elimination reactions to occur, the leaving groups and hydrogen atom of the adjacent carbon atom must be anticoplanar, which means the dihedral angle between them must be 1800. Due to this,
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
This reaction is an example of conjugate addition of a nucleophile to an a,ß-unsaturated carbonyl.
LOCH3
H20
H3C
H3C°
OCH3
OCH3
Draw the two resonance structures of the enolate anion intermediate for this reaction.
Draw Zaitsev and Hofmann products that are expected when each of the following compounds
is treated with a strong base to give an E2 ELIMINATION product.
Hint: Some compounds cannot produce both elimination products because they do not have two
beta-hydrogen atoms: in these cases only ONE product will be possible. In cases when neither
elimination products are possible, there will be NO REACTION.
?
O A
O
O
O
B
U
Br
t
Zaitsev
Hofmann
only ONE product is possible
B
only ONE product is possible
Hofmann
Zaitsev
Draw the E1 (elimination) mechanism for the reaction
Chapter 10 Solutions
EBK GET READY FOR ORGANIC CHEMISTRY
Ch. 10 - Prob. 10.1PCh. 10 - Prob. 10.2PCh. 10 - Prob. 10.3PCh. 10 - Prob. 10.4PCh. 10 - Prob. 10.5PCh. 10 - Prob. 10.6PCh. 10 - Prob. 10.7PCh. 10 - Prob. 10.8PCh. 10 - Prob. 10.9PCh. 10 - Prob. 10.10P
Ch. 10 - Prob. 10.11PCh. 10 - Prob. 10.12PCh. 10 - Prob. 10.13PCh. 10 - Prob. 10.14PCh. 10 - Prob. 10.15PCh. 10 - Prob. 10.16PCh. 10 - Prob. 10.17PCh. 10 - Prob. 10.18PCh. 10 - Prob. 10.19PCh. 10 - Prob. 10.20PCh. 10 - Prob. 10.21PCh. 10 - Prob. 10.22PCh. 10 - Prob. 10.23PCh. 10 - Prob. 10.24PCh. 10 - Prob. 10.25PCh. 10 - Prob. 10.26PCh. 10 - Prob. 10.27PCh. 10 - Prob. 10.28PCh. 10 - Prob. 10.29PCh. 10 - Prob. 10.30PCh. 10 - Prob. 10.31PCh. 10 - Prob. 10.32PCh. 10 - Prob. 10.33PCh. 10 - Prob. 10.34PCh. 10 - Prob. 10.35PCh. 10 - Prob. 10.36PCh. 10 - Prob. 10.37PCh. 10 - Prob. 10.38PCh. 10 - Prob. 10.39PCh. 10 - Prob. 10.40PCh. 10 - Prob. 10.41PCh. 10 - Prob. 10.42PCh. 10 - Prob. 10.43PCh. 10 - Prob. 10.44PCh. 10 - Prob. 10.45PCh. 10 - Prob. 10.46PCh. 10 - Prob. 10.47PCh. 10 - Prob. 10.48PCh. 10 - Prob. 10.49PCh. 10 - Prob. 10.50PCh. 10 - Prob. 10.51PCh. 10 - Prob. 10.52PCh. 10 - Prob. 10.53PCh. 10 - Prob. 10.54PCh. 10 - Prob. 10.55PCh. 10 - Prob. 10.56PCh. 10 - Prob. 10.57PCh. 10 - Prob. 10.58PCh. 10 - Prob. 10.59PCh. 10 - Prob. 10.60PCh. 10 - Prob. 10.61PCh. 10 - Prob. 10.62PCh. 10 - Prob. 10.63PCh. 10 - Prob. 10.64PCh. 10 - Prob. 10.65PCh. 10 - Prob. 10.66PCh. 10 - Prob. 10.67PCh. 10 - Prob. 10.68PCh. 10 - Prob. 10.69PCh. 10 - Prob. 10.70PCh. 10 - Prob. 10.71PCh. 10 - Prob. 10.72PCh. 10 - Prob. 10.73PCh. 10 - Prob. 10.74PCh. 10 - Prob. 10.1YTCh. 10 - Prob. 10.2YTCh. 10 - Prob. 10.3YTCh. 10 - Prob. 10.4YTCh. 10 - Prob. 10.5YTCh. 10 - Prob. 10.6YTCh. 10 - Prob. 10.7YTCh. 10 - Prob. 10.8YTCh. 10 - Prob. 10.9YTCh. 10 - Prob. 10.10YTCh. 10 - Prob. 10.11YTCh. 10 - Prob. 10.12YTCh. 10 - Prob. 10.13YTCh. 10 - Prob. 10.14YTCh. 10 - Prob. 10.15YTCh. 10 - Prob. 10.16YTCh. 10 - Prob. 10.17YTCh. 10 - Prob. 10.18YTCh. 10 - Prob. 10.19YT
Knowledge Booster
Similar questions
- Answer the question below the reaction. ta The reaction above proceeds through which type of mechanism? SN2 SN1 E1 E2 OH + Excess NH4C1 H₂SO4 + H₂Oarrow_forwardis this an E1 or E2 mechanism for this reaction? What is the major product and mechanism for it?arrow_forwardWhich reaction intermediate (A or B) is more likely to form in the epoxide ring opening reaction? Reactions prefer to react through lower energy intermediates. How might you justify one structure being lower in energy than the other? Draw structures as part of your explanation why.arrow_forward
- What are the product(s) of the following ozonolysis reaction? Note: you do not need to know the mechanism of this reaction.arrow_forwardExplain the strength of the base usually determines whether a reaction follows the E1 or E2 mechanism ?arrow_forwardDrawing the Products of an SN1 Reaction Label the nucleophile and leaving group, and draw the products (including stereochemistry) of the following SN1 reaction.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning