Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Textbook Question
Chapter 1, Problem 6E
Draw an example of a bent molecule with a bond angle of near 109.5°; then draw a different bentmolecule with a bond angle of about 120°.
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A student who missed this class needs to know how to predict the bond angles and shape of a molecule from looking at its line representation. Write a concise but complete explanation for this student.
Examine the highlighted labeled bond in the structure below.
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bonds in the molecule?
O yes
no
000
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Chapter 1 Solutions
Custom eBook for Organic Chemistry
Ch. 1 - (E) What does the number (+Z) at the center of...Ch. 1 - Prob. 2CTQCh. 1 - Prob. 3CTQCh. 1 - Prob. 4CTQCh. 1 - Prob. 5CTQCh. 1 - Prob. 6CTQCh. 1 - Prob. 7CTQCh. 1 - You hear a student from a nearby group say that...Ch. 1 - Use VSEPR to explain why the HBH bond angle of BH3...Ch. 1 - Both the HCH and HCO bond angles of H2CO...
Ch. 1 - Prob. 11CTQCh. 1 - Consider the following flat drawing of methane...Ch. 1 - Use VSEPR to assign a value of (close to) 109.5,...Ch. 1 - A student draws the picture of ammonia (NH3) in...Ch. 1 - Prob. 15CTQCh. 1 - How many central atoms does the molecule H2NCH3...Ch. 1 - Indicate the bond angle and shape about each...Ch. 1 - Explain how there can be two kinds of bent:...Ch. 1 - A student makes the following statement: “The...Ch. 1 - A student who missed this class needs to know how...Ch. 1 - Prob. 1ECh. 1 - Prob. 2ECh. 1 - Consider the incomplete valence shell...Ch. 1 - How many valence electrons does a neutral a. K...Ch. 1 - Consider the molecules AlCl3 (aluminum chloride)...Ch. 1 - Draw an example of a bent molecule with a bond...Ch. 1 - Label each atom marked with an arrow with the...Ch. 1 - a model of each of the following molecules: a....
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- Draw a bond-line structure that best matches the molecule below. (White = hydrogen; yellow = fluorine; green = chlorine; red = bromine)arrow_forward2) a) Consider the following molecule . Given what you have learned about hybridization theory, draw an image or images explaining the bonding situation in this molecule. I want you to draw out all of the orbitals, hybrid orbitals and how they overlap to form the bonds in the molecule. Indicate the % s or p character in the given atomic and hybrid orbitals. Which C-C bond or bonds are the longest? In a paragraph or so explain the image or images you just drew. b) Lastly, consider the molecule below. Indicate the Molecular formula, the molar mass, label the hybridization of each atom except for hydrogen, indicate any chiral centers with a *, which bond or bonds are the shortest, identify by name of each functional group with an arrow pointing to the group.arrow_forwardcarbon is the master of hybridization, name 3 different compounds that showcase 3 different hybridization variants in the carbon atom. Include compond names, lewis diagram and the hybridization of the carbon atom. For each of the following compounds draw the lewis diagram. Include VSEPR family, the VSEPR shape? Determine the color of light emitted from an electron in a hydrogen atom that falls from n = 6 to n = 2.arrow_forward
- If the symbol X represents a central atom, Y represents outer atoms, and Z represents lone pairs on the central atom, the structure Y-X-Y could be abbreviated as XY,Z,. Classify each molecule according to its shape. Linear Bent (x 120°) Bent (x 109°) Trigonal T-shaped See-saw Square planar Square pyramidal pyramidal Answer Bank XY;Z2 XY,Z XY,Z XY,Z3 XY;Z XY,Z, XY,Z XY,Z2arrow_forwardWhat molecular geometry does VSEPR predict for the carbon and the nitrogen in methylamine (CH3NH₂)? Choose all that apply! Trigonal pyramidal Tetrahedral T-shape Trigonal planar Linear Bentarrow_forwardGive the expected bond angle of C-C-N in the molecule CH3-C≡N on VSEPR Theory?arrow_forward
- Please answer this NEATLY, COMPLETELY, and CORRECTLY for an UPVOTE. Determine the hybridization around C1, C2 and oxygen atoms. What is the expected bond angle around C1, and C2 atoms? Identify the type of bonds (σ or π) and the overlapping orbitals that form bonds A, B, and C.arrow_forwardPlease answer this NEATLY, COMPLETELY, and CORRECTLY for an UPVOTE. Determine the hybridization around C2 and nitrogen atoms. What is the expected bond angle around C2 atoms? Identify the type of bonds (σ or π) and the overlapping orbitals that form bonds A and B.arrow_forwardWhy is it less clear to see the electrons on HBrO2 molecular electron geometry than it is on something like H2O? I know there should be 20 electrons on HBrO2, but this leads me to an incorrect drawing. And with the correct drawing, I don't see where all the electrons are. It seems like there's only 10 total. What am I missing here?arrow_forward
- 14. While there are only a few basic VSEPR shapes based on electron geometry, many different VSEPR shapes can arise from different combinations of peripheral atoms and lone pairs. One such shape is the see-saw, which happens when you have a molecule of the general form AXE (where A is the central atom, X is a peripheral atom, and E is a lone pair of electrons). Draw a molecule that would have a see-saw shape (it's not important whether the molecule technically exists, but that it could exist based on the valence electrons of its atoms).arrow_forward9) HCCCO₂H, is an organic hydrocarbon. a) Draw a geometrically accurate structure so that the formal charge of each atom is zero identifying the bond angles (Draw it BIG!). b) Identify the hybridization about each atom (not H) forming a bond c) How many o or π bonds are there in this molecule d) The combustion of the hydrocarbon produces carbon dioxide and water in the gaseous state. Use average bond enthalpies to determine enthalpy of reactionarrow_forward16) Which molecule below has a trigonal planar electron geometry?arrow_forward
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