MasteringChemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties
1st Edition
ISBN: 9780321934635
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 1, Problem 44E
When astronomers observe distant galaxies, they can tell that most of them are moving away from one another. In addition, the more distant the galaxies, the more rapidly they are likely to be moving away from each other. Can you devise an hypothesis to explain these observations?
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2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
Chapter 1 Solutions
MasteringChemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties
Ch. 1 - Which statement is true about matter? a) Matter is...Ch. 1 - A chemist mixes sodium with water and witnesses a...Ch. 1 - Two samples of a compound containing elements A...Ch. 1 - A compound containing only carbon and hydrogen has...Ch. 1 - Which concept was demostrated by Rutherford’s gold...Ch. 1 - A student re-creates Millikan’s oil drop...Ch. 1 - Prob. 7SAQCh. 1 - An isotope of an element contains 82 protons and...Ch. 1 - How many electrons are in the Cr3+ ion? 24...Ch. 1 - A naturally occurring sample of an element...
Ch. 1 - Copper has an atomic mass of 63.55 amu and two...Ch. 1 - Which sample contains the greatest number of...Ch. 1 - Explain this statement in your own words and give...Ch. 1 - Explain the main goal of chemistry.Ch. 1 - What are two different ways to classify matter?Ch. 1 - How do solids, liquids, and gases differ?Ch. 1 - Explain the difference between a pure substance...Ch. 1 - Explain the difference between an element and a...Ch. 1 - Explain the difference between a homogeneous and a...Ch. 1 - Describe the scientific approach to knowledge. How...Ch. 1 - Prob. 9ECh. 1 - What observations did Antoine Lavoisier make? What...Ch. 1 - What theory did John Dalton formulate?Ch. 1 - What is wrong with the expression, “That is just a...Ch. 1 - Summarize the history of the atomic idea. How was...Ch. 1 - Prob. 14ECh. 1 - State and explain the law of definite proportions.Ch. 1 - State and explain the law of multiple proportions....Ch. 1 - What are the main ideas in Dalton’s atomic theory?...Ch. 1 - How and by whom was the electron discovered? What...Ch. 1 - Explain Millikan’s oil drop experiment and how it...Ch. 1 - Prob. 20ECh. 1 - Describe Rutherford’s gold foil experiment. How...Ch. 1 - Describe Rutherford’s nuclear model of the atom....Ch. 1 - If matter is mostly empty space, as suggested by...Ch. 1 - List the three subatomic particles that compose...Ch. 1 - What defines an element?Ch. 1 - Explain the difference between Z (the atomic...Ch. 1 - Where do elements get their names?Ch. 1 - What are isotopes? What is percent natural...Ch. 1 - Describe the two different notations used to...Ch. 1 - Prob. 30ECh. 1 - Prob. 31ECh. 1 - Explain how a mass spectrometer works. What kind...Ch. 1 - Each shape represents a type of particle (such as...Ch. 1 - Using triangles to represent one type of atom and...Ch. 1 - Classify each substance as a pure substance or a...Ch. 1 - Classify each substance as a pure substance or a...Ch. 1 - Prob. 37ECh. 1 - Complete the table. Substance Pure or mixture Type...Ch. 1 - Determine whether each molecular diagram...Ch. 1 - Determine whether each molecular diagram...Ch. 1 - Classify each statement as an observation, a law,...Ch. 1 - Classify each statement as an observation, a law,...Ch. 1 - A chemist decomposes several samples of carbon...Ch. 1 - When astronomers observe distant galaxies, they...Ch. 1 - Prob. 45ECh. 1 - An automobile gasoline tank holds 21 kg of...Ch. 1 - Two samples of carbon tetrachloride are decomposed...Ch. 1 - Two samples of sodium chloride are decomposed into...Ch. 1 - The mass ratio of sodium to fluorine in sodium...Ch. 1 - Upon decomposition, one sample of magnesium...Ch. 1 - Two different compounds containing osmium and...Ch. 1 - Palladium forms three different compounds with...Ch. 1 - Prob. 53ECh. 1 - Sulfur and fluorine form several different...Ch. 1 - Which statements are consistent with Dalton’s...Ch. 1 - Which statements are inconsistent with Dalton’s...Ch. 1 - Which statements are consistent with Rutherford’s...Ch. 1 - Which statements are inconsistent with...Ch. 1 - A chemist in an imaginary universe, where...Ch. 1 - Imagine a unit of charge called the zorg. A...Ch. 1 - Which statements about subatomic particles are...Ch. 1 - Which statements about subatomic particles are...Ch. 1 - Write isotopic symbols in the form XA (e g., C-13)...Ch. 1 - Write isotopic symbols in the form ZAX for each...Ch. 1 - Determine the number of protons and the number of...Ch. 1 - Determine the number of protons and the number of...Ch. 1 - The amount of carbon-14 in ancient artifacts and...Ch. 1 - Uranium-235 is used in nuclear fission. Determine...Ch. 1 - Determine the number of protons and the number of...Ch. 1 - Determine the number of protons and the number of...Ch. 1 - Gallium has two naturally occurring isotopes with...Ch. 1 - Magnesium has three naturally occurring isotopes...Ch. 1 - The atomic mass of fluorine is 18.998 amu, and its...Ch. 1 - The atomic mass of copper is 63.546 amu. Do any...Ch. 1 - An element has two naturally occurring isotopes....Ch. 1 - An element has four naturally occuring isotopes...Ch. 1 - Bromine has two naturally occurring isotopes...Ch. 1 - Silicon has three naturally occurring isotopes...Ch. 1 - Use the mass spectrum of europium shown here to...Ch. 1 - Use the mass spectrum of rubidium shown here to...Ch. 1 - A 7.83-g sample of HCN contains 0.290 g of H and...Ch. 1 - The ratio of sulfur to oxygen by mass in SO2 is...Ch. 1 - Use the mass spectrum of lead shown here to...Ch. 1 - Use the mass spectrum of mercury shown here to...Ch. 1 - Nuclei with the same number of neutrons but...Ch. 1 - Fill in the blanks to complete the table. Symbol z...Ch. 1 - Silver is composed of two naturally occurring...Ch. 1 - To the right is a representation of 50 atoms of a...Ch. 1 - The ratio of oxygen to nitrogen by mass in NO2 is...Ch. 1 - Naturally occurring cobalt consists of only one...Ch. 1 - A 7.36-g sample of copper is contaminated with an...Ch. 1 - The ratio of the mass of O to the mass of N in...Ch. 1 - Naturally occurring magnesium has an atomic mass...Ch. 1 - A volatile liquid (one that readily evaporates) is...Ch. 1 - The diagram to the right represents solid carbon...Ch. 1 - Use triangles to represent atoms of element A and...Ch. 1 - Identify each statement as being most like an...
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