Concept explainers
(a)
Interpretation:
Publication year and the authors of the latest edition of Compendium of Chemical Terminology available in IUPAC website should be located.
(b)
Interpretation:
Definition and symbology of biasstated in Compendium of Chemical Terminology available in IUPAC website should be located and compared with the definition and symbology in the book chapter.
(c)
Interpretation:
Definition and symbology of detection limit stated in Compendium of Chemical Terminology available in IUPAC website should be located and compared with the definition and symbology in the book chapter.
(d)
Interpretation:
Differences between calibration sensitivity and analytical sensitivity should be stated.
(d)
Interpretation:
Calibration sensitivity, analytical sensitivity of each concentration, coefficient of variation for mean signal values of each replicate set and the detection limit for the method should be determined.
Concept introduction:
Following formulae should be used to determine each required numerical quantity.
For calibration sensitivity (
For analytical sensitivity (
For coefficient variation (CV):
For Detection limit (
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Chapter 1 Solutions
Principles of Instrumental Analysis, 6th Edition
- Many common materials that we ingest, though quite safe in reasonable quantities, become toxic when taken in very large doses. A measure of toxicity is the LD50 value (Lethal Dose, 50%). It is the quantity of material, expressed in mg of material per kg of subject-body-weight that, if administered to a population of subjects, would cause 50% of the population to die. The LD50 value for FD&C Red Dye No. 40 is >10,000 mg/kg in rats. Assume that the LD50 value for humans is the same as for rats. Calculate the number of mg of Allura Red present in an 9 fluid ounce glass of the beverage you used in this lab and use this calculation to determine the number of such glasses of Allura Red sports drink required to reach the LD50 of 10,000 mg of Allura Red/kg body weight. Assume that the concentration of Allura Red in the beverage is 0.000038 M and the person has a body weight of 175 lbs. The molar mass of Allura Red is 496.42 grams/mol 1 fl oz = 29.5735 mL 2.205 lbs = 1 kg You may assume…arrow_forwardMany common materials that we ingest, though quite safe in reasonable quantities, become toxic when taken in very large doses. A measure of toxicity is the LD50 value (Lethal Dose, 50%). It is the quantity of material, expressed in mg of material per kg of subject-body-weight that, if administered to a population of subjects, would cause 50% of the population to die. The LD50 value for FD&C Red Dye No. 40 is >10,000 mg/kg in rats. Assume that the LD50 value for humans is the same as for rats. Calculate the number of mg of Allura Red present in an 8 fluid ounce glass of the beverage you used in this lab. Assume that the concentration of Allura Red in the beverage is 0.000054 M. The molar mass of Allura Red is 496.42 grams/mol 1 fl oz = 29.5735 mL Do not include units with your answer.arrow_forwardMany common materials that we ingest, though quite safe in reasonable quantities, become toxic when taken in very large doses. A measure of toxicity is the LD50 value (Lethal Dose, 50%). It is the quantity of material, expressed in mg of material per kg of subject-body-weight that, if administered to a population of subjects, would cause 50% of the population to die. The LD50 value for FD&C Red Dye No. 40 is >10,000 mg/kg in rats. Assume that the LD50 value for humans is the same as for rats. Calculate the number of mg of Allura Red present in an 9 fluid ounce glass of the beverage you used in this lab and use this calculation to determine the number of such glasses of Allura Red sports drink required to reach the LD50 of 10,000 mg of Allura Red/kg body weight. Assume that the concentration of Allura Red in the beverage is 0.000038 M and the person has a body weight of 175 lbs. The molar mass of Allura Red is 496.42 grams/mol 1 fl oz = 29.5735 mL 2.205 lbs = 1 kg You may assume…arrow_forward
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- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning