Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 1, Problem 1.11QAP
Interpretation Introduction
(a)
Interpretation:
A standard-addition plot should be created using the data given.
Concept introduction:
A commonform of standard-addition method involves adding known amounts of a standard solution to sample aliquots containing a fixed volume. Measurements taken for each solution can be used to plot a standard-addition plot.
Interpretation Introduction
(b)
Interpretation:
Using the standard-addition plot constructed, the concentration of the unknown phenobarbital sample should be determined.
Concept introduction:
In a standard-addition plot, the graph can be extrapolated to obtain thevolume of standard reagentequivalent to the amount of analyte in the sample (
Where,
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
A 5.00 mL wine vinegar was diluted to 25 mL and was titrated with 0.1198 M NaOH to determine its acidity. The endpoint was reached after addition of 31.45 mL of the NaOH solution. Calculate the % acidity of sample expressed as % acetic acid (w/w) if the density of the wine vinegar is 1.105 g/mL.
A mixture containing KCl and NaBr was analyzed by Mohr's method. A mass of 0.31011 g of the mixture was dissolved in 50 mL of water, the Na2CrO4 indicator was added, and it was titrated with a 0.11011 mol/L AgNO3 solution. The endpoint was 36.011 mL. What are the % m/m concentrations of KCl and NaBr in the mixture?
A stock solution of Na2B having a concentration of 0.1486 M is used to prepare four calibration standards, A-D in the table below, by diluting the indicated volume of this solution to a total volume of 50.00 mL.
Complete the table by entering the molarity of B2- for each standard solution. Show an illustrative calculation for tube ‘A’. Use the dilution formula and express each result to one more digit than allowed by applying the rules of significant figures.
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What volume of 0.250 M NaOH is required to react completely with 0.0100 moles of H2SO4? (a) 80.0 mL (b) 60.0 mL (c) 40.0 mL (d) 125 mLarrow_forwardAn artificial fruit beverage contains 12.0 g of tartaric acid, H2C4H4O6, to achieve tartness. It is titrated with a basic solution that has a density of 1.045 g/cm3 and contains 5.00 mass percent KOH. What volume of the basic solution is required? (One mole of tartaric acid reacts with two moles of hydroxide ion.)arrow_forwardCalcium carbonate, CaCO3, can be obtained in a very pure state. Standard solutions of calcium ion are usually prepared by dissolving calcium carbonate in acid. What mass of CaCO3 should be taken to prepare 500. mL of 0.0200 M calcium ion solution?arrow_forward
- A 25.0-mL aliquot of vinegar was diluted to 250 mL in a volumetric flask. Titration of 50.0-mL aliquots of the diluted solution required an average of 25.23 mL of 0.09041 M NaOH. Express the acidity of the vinegar in terms of the percentage (w/v) of acetic acid.arrow_forward1. Calcium in a sample solution is determined by atomic absorption spectroscopy (AAS). A stock solution of calcium is prepared by dissolving 1.834 g CaCl, 2H,0 in water and diluting to 1 litre. From this stock solution, the second stock solution is prepared by the dilution factor of 10. Three standard solutions of calcium are prepared from the second stock solution with the following dilution factor: 20 (first standard solution), 10 (second standard solution) and 5 (third standard solution). A blank solution is prepared as well. Absorbance signals of AAS are as follows: 1.5 (blank solution), 10.6 (first standard solution), 20.1 (second standard solution), 38.5 (third standard solution), 29.6 (sample solution). (Molar mass; Ca = 40.00 g mol-, CI = 35.45 g mol-, 0 = 16.00 g mol-', H = 1.00 g mol-1) a. Construct ONE (1) plot that could be used to represent the calibration curve. b. From the plot of Q1a, determine the amount of calcium in parts per million.arrow_forwardSuppose a group of students put 2.92 grams of an unknown solid acid into a 250-mL volumetric flask and filled it up to the mark with deionized water. After this they pipetted out 15.75 mL of a 1.78 M NaOH(aq) solution into another 250-mL volumetric flask and filled it up to the mark with deionized water. The students were given a pH meter that was already calibrated by their teaching assistant (T.A.) and they got the following result shown in the table below. Calculate the Molarity of the unknown solid acid. Hint: You can approximate the endpoint of the titration by taking the average volume between two consecutive titrant volume reading and you can assume that it is a 1:1 stoichiometry ratio between the acid and OH-(aq). VNaOH (mL) pH VNaOH (mL) pH 0 1.97 15 3.43 1 2.05 16 3.57 2 2.12 17 3.65 3 2.20 18 3.77 4 2.29 19 3.88 5 2.38 20 4.01 6 2.47 21 4.23 7 2.58 22 4.65 8 2.69 23…arrow_forward
- The ethyl acetate concentration in an alcoholic solution was determined by diluting a 10.00-mL sample to 100.00 mL. A 19.00-mL portion of the diluted solution was refluxed with 40.00 mL of 0.04601 M KOH: CH3 СОО С2H; + ОН — СH3 COO + C2H; ОН After cooling, the excess OH was back-titrated with 3.02 mL of 0.05056 M H2 SO4. Calculate the amount of ethyl acetate (88.11 g/mol) in the original sample in grams. Amount of ethyl acetate =arrow_forward44.0 mL of 0.140 M Na2SO4 and 25.0 mL of 0.180 M KCl. Assume that the volumes are additive. Enter your answers, separated by commas, using three significant figures. VE ΑΣΦ MNa+, Mso, ²-, MK+, Mc = ? Marrow_forwardCaculate the volume (mL) of 1.0 M potassium carbonate (K₂CO₃) needed to prepare 5.0g of the COPPER pigment. This is where the balanced chemical equation come in. You should be able to relate the moles of pigment to the moles of K₂CO₃, and from that calculate the volume of 1.0 M K₂CO₃ solution needed. Please report your value as XX.X mL (one deicmal point and no units).arrow_forward
- (1) Careless Carlie weighed her KHP sample, but forgot to bring her report sheet along, so she recorded the mass of KHP on a paper towel. During her titration, which required 18.46 mL of base, she spilled some base on her hands. She remembered to wash her hands, but forgot about the data on the towel, and used it to dry her hands. When she went to calculate the molarity of the base, Carlie discovered that she didn’t have the mass of her KHP. Her kindhearted instructor told Carlie that her base was 0.2987 M. Calculate the mass of Carlie’s KHP sample. Show calculations (2) What mass of solid NaOH would be needed to make 645 mL of Carlie’s NaOH solution? Show calculations.arrow_forwardThe active ingredient in a certain toilet cleaner that claims to 'remove lime scale and rust' is hydrochloric acid of approximate concentration 10.9 mol/L. To analyze this toilet cleaner, a quality control chemist first delivered a 10-mL aliquot of the toilet cleaner into a 250-mL volumetric flask, then made up the diluted solution. She then titrated a 25 mL aliquot of this diluted solution against standard sodium hydroxide solution of concentration 0.46 mol/L. The expected titre (or volume of the titrant in mL) would be approximately:arrow_forwardThanks so much!arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning