
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Transcribed Image Text:Suppose the reduction of nitric oxide proceeds by the following mechanism:
step
elementary reaction
rate constant
1 H,(g) + 2 NO(g) → N20(g) + H,O(g)
k1
2
H2(g) + N,0(g) →
N,(g) + H,O(g)
k2
Suppose also k,«k,. That is, the first step is much slower than the second.
Write the balanced
chemical equation for the
overall chemical reaction:
Write the experimentally-
observable rate law for the
overall chemical reaction.
rate = k||
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of k, k2,
and (if necessary) the rate
constants k.1 and k.2 for
the reverse of the tae
k =
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