Determine the rate law and the rate constant for this reaction. 13.125. The table contains reaction rate data for the reaction 2 NO(g) + Cl;(g)→ 2 NOCI(g) Initial Rate Experiment [NO], (M) [CI]o (M) (M/s) 1 0.20 0.10 0.63 0.20 0.30 5.70 3. 0.80 0.10 2.58 4 0.40 0.20 Predict the initial rate of reaction in experiment 4. 13.126. An important reaction in the formation of photochemical is the reaction between ozone and NO: smog NO(g) + O;(g) →NO;(g) + O,(g)

For A⟶products, time and concentration data were collected and plotted as shown. [A] (M) t (s) 0.750 00.0 0.596 30.0 0.473 60.0 0.376 90.0       Determine the reaction order, the rate constant, and the units of the rate constant. order=       k=     units

Consider the following general reaction for which gases A and B are mixed in a constant volume container: A(g) + B(g) -> C(g) + D(g) Match what happens to the rate of the reaction under the following changes: (consider each change separately) v all of gas B is removed from the container more gas A is added to the container the temperature of the container is increased there is no change to the reaction rate ya catalyst is added to the container I. the reaction proceeds at a faster rate v gas D is also added to the container the reaction proceeds at a slower rate II. some of gas B is removed from the container Iy the reaction does not proceed at all the volume of the container is increased

2. Consider the reaction: NH4 (aq) + 2NO2 (aq) → N2(g) + 2H2O[g) Rate = k[NH4*][NO2] Which of the following reaction conditions will generally result in a longer reaction time? O Adding a catalyst to the reaction mixture. O Placing the reaction mixture in a hot water bath. O Increasing the concentration of any reactants. O Adding distilled water to the mixture.