Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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- Hypothetical elements A2 and B2 react according to the following equation, forming the compound AB. A2(aq)+B2(aq)2AB(aq);H=+271kJ/mol If solutions A2(aq) and B2(aq), starting at the same temperature, are mixed in a coffee-cup calorimeter, the reaction that occurs is a exothermic, and the temperature of the resulting solution rises. b endothermic, and the temperature of the resulting solution rises. c endothermic, and the temperature of the resulting solution falls. d exothermic, and the temperature of the resulting solution falls. e exothermic or endothermic, depending on the original and final temperatures.arrow_forwardWhen one mole of ethylene gas, C2H4, reacts with fluorine gas, hydrogen fluoride and carbon tetrafluoride gases are formed and 2496.7 kJ of heat are given off. What is Hf for CF4(g)?arrow_forwardIn a calorimetric experiment, 6.48 g of lithium hydroxide, LiOH, was dissolved in water. The temperature of the calorimeter rose from 25.00C to 36.66C. What is H for the solution process? LiOH(s)Li(aq)+OH(aq) The heat capacity of the calorimeter and its contents is 547 J/C.arrow_forward
- Graphite is burned in oxygen to give carbon monoxide and carbon dioxide. If the product mixture is 33% CO and 67% CO2 by mass, what is the heat from the combustion of 1.00 g of graphite?arrow_forwardHow much would the temperature of 275 g of water increase if 36.5 U of heat were added?arrow_forwardHow much heat is released when a mixture containing 10.0 g NH3 and 20.0 g O2 reacts by the following equation? 4NH3(g)+5O2(g)4NO(g)+6H2O(g);H=906kJarrow_forward
- How much heat is absorbed by a 44.7-g piece of leadwhen its temperature increases by 65.4°C?arrow_forwardHow much heat is released when a mixture containing 10.0 g CS2 and 10.0 g Cl2 reacts by the following equation? CS2(g)+3Cl2(g)S2Cl2(g)+CCl4(g);H=230kJarrow_forward9.89 A sample of gas is 80.0% CH4 and 20.0% C2H6 by mass. What is the heat from the combustion of 1.00 g of this mixture? Assume the products are CO2 (g) and H2O (l).arrow_forward
- A rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.arrow_forwardEnthalpy a A 100.-g sample of water is placed in an insulated container and allowed to come to room temperature at 21C. To heat the water sample to 41C, how much heat must you add to it? b Consider the hypothetical reaction,2X(aq)+Y(l)X2Y(aq)being run in an insulated container that contains 100. g of solution. If the temperature of the solution changes from 21C to 31C, how much heat does the chemical reaction produce? How does this answer compare with that in part a? (You can assume that this solution is so dilute that it has the same heat capacity as pure water.) c If you wanted the temperature of 100. g of this solution to increase from 21C to 51C, how much heat would you have to add to it? (Try to answer this question without using a formula.) d If you had added 0.02 mol of X and 0.01 mol of Y to form the solution in part b, how many moles of X and Y would you need to bring about the temperature change described in part c. e Judging on the basis of your answers so far, what is the enthalpy of the reaction 2X(aq) + Y(l) X2Y(aq)?arrow_forwardThe equation for the fermentation of glucose to alcohol and carbon dioxide is: C6H12O6(aq) 2C2H5OH(aq) + 2CO2(g) The enthalpy change for the reaction is 67 kJ. Is this reaction exothermic or endothermic? Is energy, in the form of heat, absorbed or evolved as the reaction occurs?arrow_forward
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