Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Question
Sighting along the C2-C3 bond of the 2-methylbutane, draw the Newman projection of
conformational isomer. State the most stable conformer
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- Fill in the blanks: cis-1,3-Dimethylcyclohexane has two different chair conformations: one withboth methyl groups in __________ positions and one with both methyl groups in ____________ positions.arrow_forwardConsider 1-bromo-2-methylpropane and draw the following. (a) The staggered conformation(s) of lowest energy (b) The staggered conformation(s) of highest energyarrow_forwardThe diaxial conformation of cis-1, 3-dimethylcyclohexane is approximately 23 kJ/mol (5.4 kcal/mol) less stable than the diequatorial conformation. Draw the two possible chair conformations, and suggest a reason for the large energy difference.arrow_forward
- Consider the molecule 1-bromo-2-methylbutane. C3 and C4 should be drawn as Et as in theexample. This group is called an ethyl group and can be considered a sphere about twice the sizeof a methyl group. Draw the following Newman projections sighting down the C1C2 bond... a. The lowest potential energy conformation. b. The highest potential energy staggered conformation.arrow_forwardPertanyaan yang ada pada gambararrow_forwardDraw 2,4-dimethylhexane as a bond-line structure. Then, looking down the C3 – C4 bond, draw a Newman projection representation of the 1) lowest energy (most stable) and 2) highest energy (least stable) conformations.arrow_forward
- translate the bond-line notation structure to the Newman projection by filling int the missing groups (A, B, C, D or E) on the lines in the Newman projection so they match the conformation given in the original structure. Circle if the conformation is a staggered or eclipsed.arrow_forwardDraw a Newman projection of 1-bromo-1-chloropropane in any staggered conformation. Draw the Newman projection as if you were looking down the C2-C1 bond, with C2 in the front.arrow_forwardDraw all Newman projections of 2,2 bromopropane conformations in which the CH3 group and the H of the CHY2 group are positioned 'gauche' to each other.arrow_forward
- In the lowest energy chair conformation of cis-1,3-dimethylcyclohexane, how many axial positions are occupied by methyl groups?arrow_forward(5) Draw the most stable chair conformation of the cyclohexane shown below. CH3 CI H3C Br OH CH3arrow_forward2.Using Newman projections, draw the most stable conformation for each of the following compounds. (a) 3-methyl pentane, viewed along the C2-C3 bond (b) 3,3-dimethyl hexane, viewed along the C3-C4 bondarrow_forward
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