Which of the following is not a feature of the Born-Oppenheimer approximation? The kinetic energy operator can be expressed in different coordinate systems (Cartesian, spherical polar, etc.). The molecular wave function can be written as a product of an electronic wave function and a nuclear wavefunction. Vibrations can be treated as subject to a potential force field imposed by the electronic state. The molecular Hamiltonian is separable into two Hamiltonians, for electrons and for nuclei, that can be solved to characterize the molecular quantum state.

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Which of the following is not a feature of the Born-Oppenheimer
approximation?
The kinetic energy operator can be expressed in different
coordinate systems (Cartesian, spherical polar, etc.).
The molecular wave function can be written as a product of an
electronic wave function and a nuclear wavefunction.
Vibrations can be treated as subject to a potential force field
imposed by the electronic state.
The molecular Hamiltonian is separable into two Hamiltonians,
for electrons and for nuclei, that can be solved to characterize
the molecular quantum state.
Transcribed Image Text:Which of the following is not a feature of the Born-Oppenheimer approximation? The kinetic energy operator can be expressed in different coordinate systems (Cartesian, spherical polar, etc.). The molecular wave function can be written as a product of an electronic wave function and a nuclear wavefunction. Vibrations can be treated as subject to a potential force field imposed by the electronic state. The molecular Hamiltonian is separable into two Hamiltonians, for electrons and for nuclei, that can be solved to characterize the molecular quantum state.
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