Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- 7arrow_forwardIsomerization reaction is the chemical process by which a compound is transformed into any of its isomeric forms with the same chemical composition but with different structure or configuration and, hence, generally with different physical and chemical properties. For an example, propene or propylene can be converted into cyclopropane in an isomerization reaction. Assume 255 g of propene (propylene) are converted into cyclopropane at 25 °C as shown below: C:H«(g, propylene) – C:H<(g, cyclopropane) Calculate the change in enthalpy by showing each step by using the related enthalpy of combustion and formation also with the Hess's law for the above mentioned condition by using the data given below: 3C(s) + 3H¿(g) → C3H6 (g,propylene) AH° = +20.42 kJ/ mol C(s) + 02(g) → CO2(g) AH° = -393.51 kJ/ mol H;(g) + 02(9) → H,0(1I) AH° = -285.83 kJ/ mol C3H.(g,cyclopropane) + 4 0,(g) → 3C0,(g) + 3H,0(1) AH° = -2091.00 kJ/ molarrow_forwardThe combustion of ethane (C₂H6) in air gave the following balanced actual combustion reaction: C₂H6+ a (O₂ + 3.76 N₂) →→1.8 CO₂ + 0.2 CO + 3H₂O + (a - 3.4) O₂ + 3.76a N₂ If the number of moles of O2 supplied is a = 6.75, what is the absolute humidity of the products? Express your answer in kg v/kg dg.arrow_forward
- Q29arrow_forwardUrea (from urine) hydrolyzes slowly in the presence of water to produceammonia and carbon dioxide. C2(NH2)2(aq) + H2O(l) → CO2(g) + 2NH3(g) What is the standard entropy change, in J/K, for this reaction when 1mol of urea reacts.arrow_forwardHydrazine, N,H4 , has been used as a rocket fuel because its reaction with oxygen is extremely exothermic: (a) N2H40) + O2(g) → N2(g) + 2H2O(g) AH = – 534.0 kJ The enthalpy change for the vaporization of water is given by: (b) H2O1)→ H2O(8) AH = 40.7 kJ Calculate the enthalpy change that would result if the water were produced in liquid rather than the gaseous form. N2H4(1) + O2(g) → N2(g) + 2H2O(1) ΔΗ- (Round off answer to the second decimal place.)arrow_forward
- please can you solve allarrow_forwardA petrochemical plant in Island C produces formaldehyde (CH2O) industrially by the catalytic oxidation of methanol (CH3OH). The following is the chemical reaction: CH3OH + ½O2 → CH2O + H2O --- (1) Unfortunately, a significant portion of the formaldehyde will react with oxygen to produce CO and H2O. The following is the side reaction: CH2O + ½O2 → CO + H2O --- (2) Assume twice the stoichiometric amount of air needed for oxidation (all chemical reactions) is fed to the reactor. The conversion of methanol is 90% in the reactor. The outlet stream of the reactor was analysed and found to be 150 kg/hr of formaldehyde, 30 kg/hr of CO and other components.(i) Determine the mass flowrate (kg/hr) of Stream A. (ii) Determine the molar flowrate (kg-moles/hr) of Stream B (iii) Determine the mass flowrate (kg/hr) of water in the outlet stream.arrow_forward(a) Consider the following chemical reaction: 3FE203(s) + CO(g) → 2Fe304(s) + CO2(g) AH° = ? Use the following thermochemical data to determine the enthalpy change of this reaction. (6) 2FE2O3 (s) AH° = -1652 kJ 4Fe(s) + 302(g) C(s,graphite) + ½O2(g) → CO(g) 3Fe(s) + 202 (g) → CO2(g) AH° = -110.5 kJ Fe304(s) C(s,graphite) + O2(g) AH° = -1117 kJ AH° = +395.5 kJ (b) What is the standard enthalpy of formation of carbon dioxide? (2)arrow_forward
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