Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- Prompt/Given Information: Consider a reversible isothermal expansion of vapor benzene at 450 K from 1 to 0.1 MPa. Assume that the PVT behavior of benzene obeys van der Waals equation of state. P = (RT)/(V - b) - a/V2 for benzene: a = 1884514 (cm6 * MPa)/mol2 and b = 119.47 cm3/mol For your convenience, at 450 K and 0.1 MPa the volume of vapor benzene is 37025 cm3/mol, and at 450 K and 1 MPa it is 3312.4 cm3/mol. R = 8.314 (MPa*cm3)/(mol*K). Note: 1 cm3*MPa/mol = 1 J/mol Question: What is the change of internal energy? What would be the change of internal energy if the gas was ideal?arrow_forwardThe vapor pressure of cyclohexane at 300 K is 0.14139 bar. What is the phase of cyclohexane at 310 K and 0.14139 bar? a) superheated vapor b) compressed liquid c) saturated vapor d) saturated liquid e) two-phase mixture f) We need more information.arrow_forward5.20. Multistage stripper. A stripper at 50 psia with three equilibrium stages strips 1,000 kmol/h of liquid at 300°F with the following molar composition: 0.03% Cı, 0.22% C2, 1.82% C3, 4.47% nC4, 8.59% nC, 34.87% nCio. The stripping agent is 1,000 kmol/h of superheated steam at 300 F and 50 psia, Use the Kremser equation to estimate the com positions and flow rates of the stripped liquid and exiting rich gas Assume a K-value for Cio of 0.20 and that no steam is absorbed. Calculate the dew-point temperature of the exiting gas at 50 psia. If it is above 300°F, what can be done?arrow_forward
- Question: A vapor/liquid experiment for the carbon disulfide(1) + chloroform(2) system has provided the following data at 298 K: P1sat = 46.85 kPa, P2sat = 27.3 kPa, x1 = 0.2, y1 = 0.363, and P = 34.98 kPa. Estimate the dew pressure at 298 K and y1 = 0.6, using the Van Laar equation. Request: Can you please help me with creating an algorithm to solve this problem. This is related to Thermodynamics by the way. Thank you!arrow_forwardHow many intensive variables are necessary to completely specify the state of pure water and pure glycerol at temperatures above 18 degrees C. What are they? If the pressure is fixed at 1 bar, how many intensive variables are necessary?arrow_forwardSketch very roughly the phase diagrams for water and carbon dioxide and use them to answer this question: at a pressure of X atmospheres and a temperature Y degrees Kelvin,what is the phase of water, and what is the phase of carbon dioxide Y=9.43 X=943arrow_forward
- Please badly need help with this one. Will give upvote for the answer please.arrow_forwardPrompt/Given Information: Consider a reversible isothermal expansion of vapor benzene at 450 K from 1 to 0.1 MPa. Assume that the PVT behavior of benzene obeys van der Waals equation of state. P = (RT)/(V - b) - a/V2 for benzene: a = 1884514 (cm6 * MPa)/mol2 and b = 119.47 cm3/mol For your convenience, at 450 K and 1 MPa the volume of vapor benzene is 3312.4 cm3/mol, and at 450 K and 0.1 MPa it is 37025 cm3/mol. R = 8.314 (MPa*cm3)/(mol*K). Note: 1 cm3*MPa/mol = 1 J/mol Question: Calculate the work done to the system? Calculate the work for the system if the gas was ideal?arrow_forward
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