Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Question
Construct the phase diagram for benzene near its triple point at 36 Torr and 5.50°C using the following data: - \( \Delta_{\text{fus}} H = 10.6 \, \text{kJ mol}^{-1} \) - \( \Delta_{\text{vap}} H = 30.8 \, \text{kJ mol}^{-1} \) - \( \rho_{\text{solid}} = 0.891 \, \text{g cm}^{-3} \) - \( \rho_{\text{liquid}} = 0.879 \, \text{g cm}^{-3} \) At a minimum, compute the slopes of the coexistence curves. Assume that the vapor behaves ideally.
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Transcribed Image Text:Construct the phase diagram for benzene near its triple point at 36 Torr and 5.50°C using the following data: - \( \Delta_{\text{fus}} H = 10.6 \, \text{kJ mol}^{-1} \) - \( \Delta_{\text{vap}} H = 30.8 \, \text{kJ mol}^{-1} \) - \( \rho_{\text{solid}} = 0.891 \, \text{g cm}^{-3} \) - \( \rho_{\text{liquid}} = 0.879 \, \text{g cm}^{-3} \) At a minimum, compute the slopes of the coexistence curves. Assume that the vapor behaves ideally.
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Step 1: The P-T diagram of a pure substance(Benzene)
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Step 2: Clapeyron equation
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Step 3: The slope of the fusion curve
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Step 4: The slope of the vapourisation curve
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Step 5: The slope of the sublimation curve
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