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Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta within the Lewis acid/base model.

Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta within the Lewis acid/base model.

Biochemistry
Biochemistry
9th Edition
ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
Section: Chapter Questions
Problem 1P
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Some different views of an octahedral symmetry metal complex 1 1 3 6. 2 1 4 View down a C, axis View down a C, axis View down a C,axis E 8C, 6C, 6C, 3C, i On i 6S, 85, 30, 604 A1g 1 1 1 1 1 1 1 1 1 -1 -1 1 Az8 1 1 -1 -1 1 Eg 2 z², x² - y? -1 0. -1 -1 -1 1 -1 -1 (xy, xz, yz) T2g -1 -1 1 1 -1 -1 A1u 1 1 1 -1 -1 -1 -1 A2u 1 -1 -1 1 -1 -1 -1 1 E -2 1 -2 -1 2 (x, y, z) -1 1 -1 -3 -1 1 3 T2u 1 -1 -1 -3 1 -1 The octahedral character table above may be useful for the following questions. 1. 1. 3. 3. 1. 2. 3. 1. 2)
Transcribed Image Text:Some different views of an octahedral symmetry metal complex 1 1 3 6. 2 1 4 View down a C, axis View down a C, axis View down a C,axis E 8C, 6C, 6C, 3C, i On i 6S, 85, 30, 604 A1g 1 1 1 1 1 1 1 1 1 -1 -1 1 Az8 1 1 -1 -1 1 Eg 2 z², x² - y? -1 0. -1 -1 -1 1 -1 -1 (xy, xz, yz) T2g -1 -1 1 1 -1 -1 A1u 1 1 1 -1 -1 -1 -1 A2u 1 -1 -1 1 -1 -1 -1 1 E -2 1 -2 -1 2 (x, y, z) -1 1 -1 -3 -1 1 3 T2u 1 -1 -1 -3 1 -1 The octahedral character table above may be useful for the following questions. 1. 1. 3. 3. 1. 2. 3. 1. 2)
Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta within the Lewis acid/base model. (The Generic Octahedral Metal Complex information above may be useful in doing this.) Eg symmetry SALC (ligand = NH3) %3D V [ ChoosN Pi Base Sigma Base Eg symmetry SALC (ligand = 1-) Pi Acid Sigma Acid T2g symmetry SALC (ligand = 1-) [ Choose ] T2g symmetry SALC (ligand = CO) [ Choose ]
Transcribed Image Text:Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta within the Lewis acid/base model. (The Generic Octahedral Metal Complex information above may be useful in doing this.) Eg symmetry SALC (ligand = NH3) %3D V [ ChoosN Pi Base Sigma Base Eg symmetry SALC (ligand = 1-) Pi Acid Sigma Acid T2g symmetry SALC (ligand = 1-) [ Choose ] T2g symmetry SALC (ligand = CO) [ Choose ]
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