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Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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
Transcribed Image Text:Use the van der Waals equation of state to calculate the pressure of 3.90 mol of N,0 at 453K in a 5.80 L vessel. Van der
Waals constants can be found in the van der Waals constants table.
atm
Use the ideal gas equation to calculate the pressure under the same conditions.
P =
atm
In a 17.00 L vessel, the pressure of 3.90 mol of N,0 at 453 K is 8.53 atm when calculated using the ideal gas equation and
8.42 atm when calculated using the van der Waals equation of state.
Why is the percent difference in the pressures calculated using the two different equations greater when the gas is in the
5.80 L vessel compared to the 17.00 L vessel?
O The molecular volume is a larger part of the total volume of the 5.80 L vessel.
O The molecular volume is a smaller part of the total volume of the 5.80L vessel.
The attractive forces between molecules become less of a factor at the higher pressure in the 5.80L vessel.
O The attractive forces between molecules become a greater factor at the higher pressure in the 5.80 L vessel.
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