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- Q17. Compound 1 can undergo an intramolecular reaction to give cyclic product 2. Using curly arrows, show the mechanism of this reaction – note that the mechanism involves more than one elemental step - and draw the structure of 2; chemical formula is provided as guidance. H2N. C5H9NO CH;OH 25) Complete the following reactions a) cH3- CHz COOH + b) cH3 - CHz CooHt LioH - c) CH3 COOH + Hg CO3Q17. Compound 1 can undergo an intramolecular reaction to give cyclic product 2. Using curly arrows, show the mechanism of this reaction – note that the mechanism involves more than one elemental step - and draw the structure of 2; chemical formula is provided as guidance. H2N. C5H9NO CH3OH 2
- 1) Draw the complete electron-pushing arrow mechanism for the following reductions. Explain, using resonance contributors (structures), the regiochemistry that results in each case. OMe Na, MeOH ? NH3 CHO Na, MeOH ? NH3III. Give a detailed mechanism for the following reaction: OH ОНIdentify the major product of the following reaction sequence. 1) [H*], H₂NNH2, (-H₂O) 2) KOH/H₂O, heat HO₂C HO₂C HO CO,H OH OH There is no reaction under these conditions or the correct product is not listed here.
- Complete the reaction scheme below. Show all reagents and intermediates. No reaction is a possible answer. 1) CH3CH2M9B CH3OH H+ (ехcess) но 2) H30*, H2O B A OCH3Q6. Propose a mechanism for the following reaction: Br CH3O + BrQ17. Compound 1 can undergo an intramolecular reaction to give cyclic product 2. Using curly arrows, show the mechanism of this reaction – note that the mechanism involves more than one elemental step - and draw the structure of 2; chemical formula is provided as guidance. H,N. CsHgNO + CH;OH 2
- 1) For the below transformation, what will be the products? Provide a mechanism for b) a) b) N CH3CH2 H Room Temp 1. DMF, POCI3 2. H2O Na in THF Br2. Fill in the missing reagent and/or product for each of the following reactions. 2 요 H OEt H. CHO ? C6H5CHO -OH, H₂O CN CN NaOEt, EtOH 1) NaOEt 2) H3O+ 1) NaOEt 2) H3O+ 1) NaOEt 2) H₂O H+, H₂O ? OEto OH 3) Please draw the structures that correspond to omitted structure for each of the following synthetic sequences. HO Cro3 Cl (d) Cro3 (a) Product `OH Product OH H30 H30 HO PCC Cl PCC (b) Product (e) `OH Product "OH HO РСС NABH4 (f) Starting Material Product 'OH ELOH