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- The Friedel-Crafts Alkylation of p-xylene n-propyl bromide can result in an isopropyl as well as n-propyl substitution. A) Write the chemical equation involved in this reaction. B) Which will be the major and minor product? What do you expect will be the ratio of n-propyl to isopropyl substitution for p-xylene?What is the skeletal structure of the alkyl halide that forms the following alkene as its only product in an elimination reaction?An unknown alkyne is treated with ozone (followed by hydrolysis) to yield acetic acid and carbon dioxide. What is the structure of the alkyne?
- 3-Hexanone can be synthesized from butanal and ethane using a Grignard reaction. The first step must be O creation of a carbocation O protonation of an oxygen nucleophilic attack of the aldehyde free radical halogenation preparation of an acetylideWhy aldehydes and ketones do not undergo nucleophilic substitution reaction?The coupling of an alkyne with an aryl halide in the presence of a palladium catalyst and triethylamine is called a Sonogashira reaction. What reactants couple to form this product?
- What is the major organic product obtained from the reaction of toluene with fuming sulfuric acid?The relative rates of reaction of ethane, toluene, and ethylbenzene with bromine atoms have been measured. The most reactive hydrocarbon undergoes hydrogen atom abstraction a million times faster than does the least reactive one. Arrange these hydrocarbons order of decreasing reactivity.The SN2 reaction is an example of a nucleophilic substitution reaction. Draw the structure of the two reactants and the mechanism of the reaction. The reaction is 1-bromo-3-ethylpentane reacts with cyclohexanol under basic conditions.
- How many different monosubstituted products are possible when ethylcyclopentane reacts with one equivalent of bromine in the presence of light?1) The carbon-oxygen double bond present in aldehydes and ketones is very polar. What does this mean and how does it arise? 2) The carbon-oxygen double bond is readily attacked by nucleophiles like cyanide ions or ammonia. (i) What do you understand by the term nucleophile? (ii) Which part of the carbon-oxygen double bond is attractive to nucleophiles? 3) Why is there a difference between aldehydes and ketones in their response to oxidizing agents such as potassium dichromate(VI) solution acidified with dilute sulfuric acid?Explain why methyl trifluoroacetate, CF3CO2CH3, is more reactive than methyl acetate, CH3CO2CH3, in nucleophilic acyl substitution reactions.