Question 19Please predict the products for each of the following reactions.Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).If a mixture of enantiomers is formed, please draw all the enantiomers.Br2CH3OH1.032. DMSKMnO4, NaOHcoldHIMCPBA1. OsO42. H₂O₂1918171615CH3CO₂H(peroxyacid)1413Pd or Pt (catalyst)201212 11 10D₂ (deuterium)HBrROOR (peroxide)H₂O8H2SO4HCI1. BH3.THF2. H₂O2, NaOHBr2Br2H₂OBH3⚫THFABсDOCH3BrBrOCH3'BrOCH3OCH3BrOCH3BrBrOCH3of de det ofBr"OCH3OCH3""BrАA BCO D

Alkenes are unsaturated hydrocarbons that have double bonds due to which they are reactive and…

Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both) If a mixture of enantiomers is formed, please draw all the enantiomers. H₂ Pd or Pt (catalyst) HBr cold 1.03 2. DMS KMnO4, NaOH CH₂OH 1.03 Br₂ 2. (CH3)2S 20 19 18 17 HI 16 15 2 14 13 12 11 10 MCPBA 1. Os04 2. H₂O₂ CH3CO_H (peroxyacid) 1. MCPBA 2. H₂O* A B HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 34 9 569 Br2 H₂O BH3.THF Bra Pd or Ni (catalyst) D2 (deuterium) EtOH C D OCH ☑OCH 'Br Br OCH Br OCH Br OCH3 OCH3 Br Br OCH "OCH OCH3 "Br Br

Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both) If a mixture of enantiomers is formed, please draw all the enantiomers. H₂ Pd or Pt (catalyst) HBr cold 1.03 2. DMS KMnO4, NaOH CH₂OH 1.03 Br₂ 2. (CH3)2S 20 19 18 17 HI 16 15 2 14 13 12 11 10 MCPBA 1. Os04 2. H₂O₂ CH3CO_H (peroxyacid) 1. MCPBA 2. H₂O* A B HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 34 9 569 Br2 H₂O BH3.THF Bra Pd or Ni (catalyst) D2 (deuterium) EtOH C D OCH ☑OCH 'Br Br OCH Br OCH Br OCH3 OCH3 Br Br OCH "OCH OCH3 "Br Br

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question 18 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 1.03 18 17 16 15 14 13 19 2. DMS KMnO4, NaOH cold HI mCPBA 1. OsO4 2. H₂O₂ CH CO;H (peroxyacid) MCPBA 2. H₂O Pd or Ni (catalyst) D2 (deuterium) 12 11 10 Pd or Pt (catalyst) 8 HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 H₂O BH3⚫THF Br2 O A B A OH ein C U D ОН B D
ABCD Question 17 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br₂ CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. Os04 2. H₂O₂ CHCO H 20 18 17 16 15 (peroxyacid) B Pd or Pt HBr ROOR (peroxide) H₂O H₂SO4 HCI 14 13 12 11 10 3 1. BH, THF 2. H₂O₂, NaOH Br₂ Br2 H₂O BH3⚫THF D OH OH OH OH OH OH OH "OH OH OH OH фон OH OH OH OH 'OH OH OH "OH
Question 4 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH3OH 1.03 2. DMS KMnO4, NaOH cold HI 2. (CH3)2S 18 17 16 15 14 H₂ Pd or Pt (catalyst) 20 1 2 13 12 11 10 MCPBA 1. OsO4 2. H₂O2 CH3CO₂H (peroxyacid) MCPBA A ४.४ A B C D B H₂O HBr ROOR (peroxide) H₂O 8 H2SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF Br Pd or Ni (catalyst) D2 (deuterium) EtOH OH OH с OH D OH "OH ४.४ "OH
Question 13 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Brz CH3OH 1.03 2. DMS KMnO4, NaOH cold HI 19 18 17 16 15 14 13 Pd or Pt (catalyst) 201 MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) MCPBA 2. H₂O+ HBr ROOR (peroxide) H₂O 9 12 11 10 Pd or Ni (catalyst) D₂ (deuterium) FIOH H2SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF A B с D Α В ABCD OH "OH ४.४
Question 17 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. A Bra CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI 18 17 16 15 14 mCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) B 12 Pd or Pt (catalyst) 20 1 2 HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH3.THF 13 12 11 10 9 2. H₂O2, NaOH Br2 Pd or Ni (catalyst) Br₂ H₂O BH3⚫THF с D OH OH OH OH OH OH ""OH "OH OH OH OH OH OH œ œ œ œ œ OH "OH OH OH OH 'OH A B ос D
Question 19 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. HBr ROOR (peroxide) H₂O Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. OsO4 2. H₂O₂ 18 17 16 CH3CO₂H (peroxyacid) 15 14 Pa or Pt (catalyst) 19 20 1 2 13 12 11 10 Pd or Ni (catalyst) D₂ (deuterium) (deuterium) A B H2SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH Br2 Br2 BH3⚫THF H₂O 0 D OCH3 а Br OCH3 Br OCH3 Br Br OCH3 Br OCH3 Br OCH3 de de de of Br OCH3 OCH3 'Br ABCD
Question 5 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 2. (CH3)2S CH3OH 1.03 2. DMS KMnO4, NaOH cold HI μ Pd or Pt (catalyst) 20 1 19 18 17 16 15 14 13 HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3.THF 12 9. 11 10 MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF Br- FIOH Pd or Ni (catalyst) D₂ (deuterium) A B 8.8 A B с D 0 H D ४.४
Question 2 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O2 CH3CO₂H (peroxyacid) MCPBA 2. (CH3)2S 20 19 18 17 16 15 H₂ Pd or Pt (catalyst) HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH 14 Br2 13 12 11 10 H₂O Br2 BH3⚫THF Bra F+OH Pd or Ni (catalyst) D2 (deuterium) A B C D Br Br Br ď ď H "Br "Br 3.8 Α ABCD
Question 19 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br₂ CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI 18 19 20 1 2 17 16 HBr ROOR (peroxide) H₂O H₂SO4 HCI MCPBA 1. Os04 2. H₂O₂ (peroxyacid) 15 14 13 12 11 10 1. BH3.THF 2. H₂O2, NaOH Br2 H₂O BH3.THF Br₂ B D OCH3 Br Br ď ď ď ď Br OCHS OCH Br OCHS Br ४.४ o de de de Br OCHS OCH ABC о D
Question 15 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. (CH3)2S Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI Pd or Pt (catalyst) 20 1 2 19 18 17 16 15 14 13 12 11 10 MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) MCPBA HBr ROOR (peroxide) H₂O H2SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF Br2 FIOH Pd or Ni (catalyst) D₂ (deuterium) A B с 000 ABCD ....O D
Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Question 5 2. (CH3)2S Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA Pd or Pt (catalyst) HBr ROOR (peroxide) H₂O 20 12 19 18 17 16 15 1. OsO4 2. H₂O2 CH3CO₂H 14 13 (peroxyacid) 12 11 10 H2SO4 HCI 5 1. BH3.THF 6 2. H₂O2, NaOH Br2 Pd or Ni (catalyst) D2 (deuterium) FIOH MCPBA 2. H₂O Br2 H₂O BH3⚫THF A B с D 8.8 A B C 3.8 ४.४
Question 17 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Bra CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI A 19 18 17 16 H2 Pd or Pt (catalyst) 20 1 2 HBr ROOR (peroxide) H₂O H₂SO4 HCI 6 1. BH₁.THF 2. H₂O2, NaOH 8 Br2 Br2 H₂O BH3⚫THF MCPBA 1. OsO4 2. H₂O₂ Неоно (peroxyacid) MCPBA 15 14 13 12 11 10 Pd or Ni (catalyst) (deuterium) B 0 D 44444 OH OH OH OH OH de de de de de OH 'OH OH OH Α ABCD