Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- THERMODYNAMICS: A 1.71 g sample of acetic acid (HC2H302) was burned in excess oxygen in a bomb calorimeter. The calorimeter, which alone had a heat capacity of 2.67 kJ/°C, contained 7 g of water. The temperature of the calorimeter and its contents increased from 23.09°C to 27.95°C. What is AH (in kJ) for the combustion per 1.00 mol of acetic acid? MW of acetic acid is 60 g/mol. (Round off the final answer to ONE decimal place. Do not include the unit.)arrow_forwardGram for gram, fats in food have much more chemical energy than sugar. One component of fat is stearic acid, C18H36O2. When a sample of 1.02 g of stearicd acid was burned completely in a bomb calorimeter, the temperature of the calorimeter rose by 4.26 oC. The heat capacity of the calorimeter was 9.43 kJ/oC. Calculate the molar heat of combustion of stearic acid in kilojoules per mole. answer: (-11189 kJ/mol)arrow_forwardIn a laboratory investigation into the neutralization reaction; HNO3 (aq) + NaOH(s) → NaNO3 (aq) + H2O (l) a researcher adds 5.3 g of solid sodium hydroxide to 200.0 mL of 1.0 M nitric acid solution in a polystyrene calorimeter. The temperature changes from 21.0°C to 28.5°C. Calculate the molar enthalpy of neutralization of sodium hydroxide.arrow_forward
- 4. The reaction of 250.0 mL of a 1.00 M hydrochloric acid solution with 250.0 mL of a 1.00 M sodium hydroxide solution was carried out in a constant pressure calorimeter. The total heat capacity of the calorimeter plus solutions was 6.45 kJ/K. The temperature of the calorimeter and solutions increased by 2.11°C. What is AH (in kJ) for the neutralization of 1.00 mol HCl(aq) by NaOH(aq)? A) -54.4 B) -21.2 +12.6 +54.4 E) -12.6arrow_forwardTHERMODYNAMICS: A 1.09 g sample of acetic acid (HC2H2O2) was burned in excess oxygen in a bomb calorimeter. The calorimeter, which alone had a heat capacity of 2.67 KJ°C. contained 7g of water. The temperature of the calorimeter and its contents increased from 24.13°C to 27.95°C. What is AH (in kJ) for the combustion per 1.00 mol of acetic acid? MW of acetic acid is 60 gimol. (Round off the final answer to ONE decimal place. Do not include the unit.)arrow_forwardIn a coffee cup calorimeter, 40.0 mL of 0.33 M nitric acid (HNO3) and 40.0 mL of 0.33 M potassium hydroxide (KOH) are mixed to observe the heat released during the neutralization reaction. Based on the data in the table, what is the enthalpy of the neutralization reaction between HNO3 and KOH? Initial temperature in the calorimeter (°C) Final temperature in the calorimeter (°C) Final mass of the neutralized solution (g) Calorimeter constant (J/C)) 21.3 23.5 79.74 4.57arrow_forward
- THERMODYNAMICS: A 1.39 g sample of acetic acid (HC2H3O2) was burned in excess oxygen in a bomb calorimeter. The calorimeter, which alone had a heat capacity of 2.67 kJ/°C, contained 753 g of water. The temperature of the calorimeter and its contents increased from 23.77°C to 27.95°C. What is AH (in kJ) for the combustion per 1.00 mol of acetic acid? MW of acetic acid is 60 g/mol. (Round off the final answer to ONE decimal place) Round your answer to 1 decimal place.arrow_forwardWhen 1.836 grams of sucrose (Molar mass 342.3 g/mol) is burned in a bomb calorimeter, the temperature of the calorimeter increases from 22.41°C to 26.63°C. If the heat capacity of the calorimeter is 4.900 kJ/°C, what is the heat of combustion of sucrose?arrow_forwardWhen 6.54 grams of Zn is placed in 500.0 mL of 1.00 M CuSO4(aq) in a coffee cup calorimeter, it reacts completely to displace copper. The temperature of the solution rises from 20.0˚C to 30.4˚C. Assume the coffee cup itself gains no heat and that the solution has the same density (1.00 g/mL) and specific heat (4.184 J/g˚C) as pure water. (a) How much heat does the solution gain during this reaction? (in J)arrow_forward
- You mix 125 mL of 0.250 M CSOH with 50.0 mL of 0.625 M HF in a coffee-cup calorimeter, and the temperature of both solutions rises from 21.70 °C before mixing to 24.59 °C after the reaction. CsOH(aq) + HF (aq) → CsF(aq) + H₂O(l) What is the enthalpy of reaction per mole of CSOH? Assume the densities of the solutions are all 1.00 g/mL, and the specific heat capacities of the solutions are 4.2 J/g. K. Enthalpy of reaction = kJ/molarrow_forward4. When 1.00 L of 1.05 M Ba(NO3)2 solution is mixed with 1.00 L of 1.10 M NazSO4 solution at 25.0°C in a coffee-cup calorimeter. The reaction is Ba(NOs)2(aq) + NazSO4(aq) → BaSO4(s) + 2NANO:(aq). The final temperature of the mixture increases to 28.1°C. Calculate the enthalpy change per mole for this process. (Assuming C=4.18 J °C' g' and density of the final solution is 1.05 g/ml).arrow_forwardTHERMODYNAMICS: A 1.96 g sample of acetic acid (HC;H3O2) was burned in excess oxygen in a bomb calorimeter. The calorimeter, which alone had a heat capacity of 2.67 kJ/°C, contained 776 g of water. The temperature of the calorimeter and its contents increased from 24.51°C to 27.95°C. What is AH (in kJ) for the combustion per 1.00 mol of acetic acid? MW of acetic acid is 60 g/mol. (Round off the final answer to ONE decimal place) Round your answer to 1 decimal place.arrow_forward
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