Suppose you burned 1.726 g of benzoic acid, C6H5 CO2H, in a constant volume calorimeter and found that the temperature increased from 22.73 °C to 34.79 °C. The calorimeter contained 673 g of water, and the bomb had a heat capacity of 805 J/K. Calculate AU per mole of benzoic acid. Specific heat of water is 4.184 J/g. K. Benzoic acid, C6H5 CO2 H, occurs naturally in many berries. Its heat of combustion is well known, so it is used as a standard to calibrate calorimeters. AU = || kJ/mol C6H5 CO₂H
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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