Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- A gas mixture contains 4.5 mol Br, and 33.1 mol F,. (a) Compute the mole fraction of Br, in the mixture. (b) The mixture is heated above 150°C and starts to react to give BrFs: Br2(g) + 5 F2(g) –→ 2 BrF;(g) At a certain point in the reaction, 2.2 mol BrF5 is present. Determine the mole fraction of Br2 in the mixture at that point.arrow_forwardThe ideal gas law describes the relationship among the volume of an ideal gas (V), its pressure (P), its absolute temperature (T), and number of moles ( n): PV = nRT Under standard conditions, the ideal gas law does a good job of approximating these properties for any gas. However, the ideal gas law does not account for all the properties of real gases such as intermolecular attraction and molecular volume, which become more pronounced at low temperatures and high pressures. The van der Waals equation corrects for these factors with the constants a and b, which are unique to each substance: (P+ ²) (V-nb) = nRT an² The gas constant R is equal to 0.08206 L.atm/(K-mol). Part A A 3.00-L flask is filled with gaseous ammonia, NH3. The gas pressure measured at 16.0 °C is 2.45 atm . Assuming ideal gas behavior, how many grams of ammonia are in the flask? Express your answer to three significant figures and include the appropriate units. View Available Hint(s) mass of NH3 = Submit ▾ Part B HÅ…arrow_forwardCalculate the density of sulfur hexafluoride gas at 410 torr and 34 °C.arrow_forward
- (a) (c) A column of water in a buret is 336 mm Hg high. How high would that column be if it were mercury instead of water? (d) In order for the pressures to be equal, density and height of a column are inversely proportional, therefore the following relationship applies: (denHg)(hHg) = (denH20)(hH20) Note: the density of mercury is 13.6 g/mL and the density of water is 1.00 g/mL. An electrolysis experiment was run for 15 minutes and 45 seconds at an average current of 189 milliamps (mA). The mass lost by the copper anode was 0.0589 grams. (b) Calculate the number of coulombs transferred. (Remember: coulomb = amps x sec) Show full calculation of the height in mercury (remember to use proper significant figures.) Calculate the moles of copper lost from the anode. Based on the moles of copper lost determined in 1c, calculate the moles of electrons transferred. Remember, the reaction at the copper anode is: Cu(s)---> Cu¹² (aq) + 2 earrow_forwardThe number of moles of CO2 in that last equation was 0.119 moles.arrow_forwardThe ideal gas law describes the relationship among the pressure P, volume V, number of moles n, and absolute temperature T of an ideal gas. Here is the relationship expressed mathematically: PV = nRT where R is a proportionality constant. The units of R are determined by the units of pressure and volume used in the equation. When bar used for pressure and L for volume, the appropriate R value is 0.08314 L bar mol-¹ K-¹. Part A How many air molecules are in a 4.05 x 3.66 x 3.05 m³ room? Assume atmospheric pressure of 1.00 bar, a room temperature of 20.0 °C, and ideal behavior. Express your answer using three significant figures. ► View Available Hint(s) VE ΑΣΦ + Review | Constants | moleculesarrow_forward
- The van der Waals equation of state was designed (by Dutch physicist Johannes van der Waals) to predict the relationship between pressure p, volume V and temperature T for gases better than the Ideal Gas Law does: p+a- |(V-nb) = nRT The van der Waals equation of state. R stands for the gas constant and n for moles of gas. The parameters a and b must be determined for each gas from experimental data. Use the van der Waals equation to answer the questions in the table below. Ar What are the units of a? What are the units of b? For water the numerical value of a is 5.464 and the numerical value of b is 0.0305. Oat ||atm Use the van der Waals equation to calculate the pressure of a sample of water at 430.0 °C with a molar volume of 4.03 L/mol. Round your answer to the correct number of significant digits. Use the Ideal Gas Law to calculate the pressure of the same sample under the same conditions. Round your answer to the correct number of significant digits. atmarrow_forwardThe average kinetic energy of the molecules in a gas sample depends only on the temperature, T. However, given the same kinetic energies, a lighter molecule will move faster than a heavier molecule, as shown in the equation for rms speed 3 RT rms speed where R = 8.314 J/ (mol·K) and M is molar mass in kilograms per mole. Note that a joule is the same as a kilogram-meter squared per second squared (kg-mIs²). What is the rms speed of O, molecules at 307 K? rms speed: m/s What is the rms speed of He atoms at 307 K? rms speed: m/sarrow_forwardAt 287 K and 1.43*10^-2 atm, the density of a gas is 1.37*10^-5 g/cm^3. (a) Find the Vrms for the gas molecules. (b) Find the molar mass of the gas.arrow_forward
- An “empty" spray can contains residual propellant gas that has a pressure of 772 torr at 23°C. The can is then heated to 475 °C. (a) What is the gas pressure in the hot can if the volume remains constant? (b) What is the gas pressure in the hot can if the can slightly expands during heating and its volume increases by 6.50%?arrow_forwarda) From the temperature-pressure data graphed in Part A, visually determine the gas pressure at a temperature of 350 K, including units. (b)From the temperature-pressure data graphed in Part A, determine the equation of the line of best fit. (C) What are the units for the slope of the line of best fit determined in question 2? (D) From the equation of the line of best fit determined in Question 2, algebraically determine the gas pressure at a temperature of 350 K, including units and a unit analysis. Note: I only need su part D solve pleasearrow_forwardKnowing that the variation in the Earth's atmosphere is given byp = p0e^-Mgy/RTwhere we consider the uniform temperature T, M the molar mass, R the gas constant, and g the constant of gravity. Show that nV = nV0e^-Mgy/RT ;where nV is the number of molecules per unit volume.arrow_forward
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