Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- The van der Waals equation of state was designed (by Dutch physicist Johannes van der Waals) to predict the relationship between pressure p, volume V and temperature T for gases better than the Ideal Gas Law does: (p + a n2/V2)(V- nb)= nRT The van der Waals equation of state. R stands for the gas constant and n for moles of gas. The parameters a and b must be determined for each gas from experimental data. Use the van der Waals equation to answer the questions in the table below. What are the units of a? What are the units of b? For ethane the numerical value of a is 5.507and the numerical value of b is 0.0651. Use the van der Waals equation to calculate the pressure of a sample of ethane at 55.0°C with a molar volume of 0.781/Lmol. Round your answer to 3 significant digits. atm Use the Ideal Gas Law to calculate the pressure of the same sample under the same conditions. Round this answer to 3 significant digits also. atmarrow_forwardThe ideal gas law allows us to predict that: As the temperature of a gas increases, the volume of the gas will increase by a proportional amount. If the amount of gas stored inside of a rigid container were increased while the temperature was held constant, the pressure would increase proportionately with the quantity of gas inside the container. As the pressure of a gas increases, the volume of the gas will increase by a proportional amount. If there is a decrease in the quantity of gas stored inside a rigid container that is maintained at constant pressure, the temperature will also decrease proportionately.arrow_forwardWhat is the pressure in kilopascals of a gas that exerts a pressure of 825 torr? Use your chart for pressure conversions. Convert 825,000 pascal, pa into torr. Give the numerical value only without the unit (the assumption is that the unit is torr). 1 atm = 760 torr 760 mmHg = 101,325 pa = 101.325 kpa = 1.01325 barr = 14.696 %3D %3D p.s.i. = 29.921 inHg (inHg and p.s.i. are approximations of the metric pressures and are subject to significant figures)arrow_forward
- The Ideal Gas Law is given by the equation: PV = nRT Where: P = pressure V = volume n = moles T = temperature in Kelvin In order to solve for the moles, n, you must multiply both sides of the equation by the same expression: PV x = nRT x The resulting equation is: n =arrow_forwardCalculate the molar mass of a gas at 316. torr and 83.0 °C if 206. ng occupies 0.206 µL. Be sure your answer has the correct number of significant figures. Note: Reference the Conversion factors for non-SI units, Fundamental constants and SI prefixes tables for additional information. g mol x10 ×arrow_forwardFor many purposes we can treat propane C3H8 as an ideal gas at temperatures above its boiling point of −42.°C Suppose the temperature of a sample of propane gas is lowered from 19.0°C to −11.0°C, and at the same time the pressure is changed. If the initial pressure was 0.70kPa and the volume increased by 45.0%, what is the final pressure? Round your answer to 2 significant digits.arrow_forward
- The ideal gas law is a limiting law, in that it is expected to hold as pressure approaches zero. Suppose the following measured values have been obtained for oxygen gas at 273.15K. Based on the data, calculate R for each pressure value and create a table of pressure and R values (i.e. you are treating R as a variable rather than a constant at this point). Then create a plot R vs p and find the “best value” of R by determining the y-intercept of a straight line fit. (Be sure to label your axes including units).arrow_forwardThe van der Waals equation of state was designed (by Dutch physicist Johannes van der Waals) to predict the relationship between pressure p, volume V and temperature T for gases better than the Ideal Gas Law does: p+a- |(V-nb) = nRT The van der Waals equation of state. R stands for the gas constant and n for moles of gas. The parameters a and b must be determined for each gas from experimental data. Use the van der Waals equation to answer the questions in the table below. Ar What are the units of a? What are the units of b? For water the numerical value of a is 5.464 and the numerical value of b is 0.0305. Oat ||atm Use the van der Waals equation to calculate the pressure of a sample of water at 430.0 °C with a molar volume of 4.03 L/mol. Round your answer to the correct number of significant digits. Use the Ideal Gas Law to calculate the pressure of the same sample under the same conditions. Round your answer to the correct number of significant digits. atmarrow_forwardThe van der Waals equation of state was designed (by Dutch physicist Johannes van der Waals) to predict the relationship between pressure p, volume V and temperature T for gases better than the Ideal Gas Law does: (p+a n2/V2) (V-nb) =nRT The van der Waals equation of state. R stands for the gas constant and n for moles of gas. The parameters a and b must be determined for each gas from experimental data. Use the van der Waals equation to answer the questions in the table below. What are the units of a? What are the units of b? For argon the numerical value of a is 1.337 and the numerical value of b is 0.0320. Use the van der Waals equation to calculate the pressure of a sample of argon at −110.0°C with a molar volume of 0.384/Lmol. Round your answer to 3 significant digits. = atm Use the Ideal Gas Law to calculate the pressure of the same sample under the same conditions. Round this answer to 3 significant digits also. =…arrow_forward
- A compound which is 39.9 % C, 13.5 % H, and 46.6 % N by mass was studied. A 0.378 g sample of the gas occupies 275 mL at 250.oC and 745 mm Hg. What is the molar mass of the gas? What is the empirical formula? What is the molecular formula?arrow_forwardSTP (standard temperature and pressure) is used as a reference point for the molar volume of an ideal gas. In the USA, most chemists, most general chemistry texts, and OWL use STP=0°C, 1 atm, where the molar volume = volume is 22.7 L/mol. Do not confuse the two. 22.4 L/mol. If the reference pressure is chosen to be 1 bar, the molar A 0.610 mol sample of methane gas occupies a volume of L at STP.arrow_forwardAccording to our modern understanding of the gas laws, there are four measurable properties (variables) of a gas. These variables are P (pressure), V (volume), T (temperature), and n (number of moles). In Boyle's experiment, which are two variables were held constant?arrow_forward
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