The reaction of solid calcium fluoride and sulfuric acid produces calcium sulfate solids and gaseous HF. The gas product is dissolved in water to form hydrofluoric acid. Fluorite ore, a source of calcium fluoride, contains 95%wt CaF2 and 5%wt SiO2. In a certain process, the ore is reacted with 93%wt aqueous sulfuric acid, supplied 15% in excess. From this, 95% of the ore dissolves in the acid. Some of the HF formed reacts with the dissolved silica in the reaction: HF reacts with SiO2 to produce H2SiF6 and liquid water. If 60%wt of hydrofluoric acid was formed when hydrogen fluoride (which exits the reactor) is dissolved in water, determine the amount of ore needed to produce one metric ton of acid.
The reaction of solid calcium fluoride and sulfuric acid produces calcium sulfate solids and gaseous HF. The gas product is dissolved in water to form hydrofluoric acid. Fluorite ore, a source of calcium fluoride, contains 95%wt CaF2 and 5%wt SiO2. In a certain process, the ore is reacted with 93%wt aqueous sulfuric acid, supplied 15% in excess. From this, 95% of the ore dissolves in the acid. Some of the HF formed reacts with the dissolved silica in the reaction: HF reacts with SiO2 to produce H2SiF6 and liquid water. If 60%wt of hydrofluoric acid was formed when hydrogen fluoride (which exits the reactor) is dissolved in water, determine the amount of ore needed to produce one metric ton of acid.
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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The reaction of solid calcium fluoride and sulfuric acid produces calcium sulfate solids and gaseous HF. The gas product is dissolved in water to form hydrofluoric acid. Fluorite ore, a source of calcium fluoride, contains 95%wt CaF2 and 5%wt SiO2.
In a certain process, the ore is reacted with 93%wt aqueous sulfuric acid, supplied 15% in excess. From this, 95% of the ore dissolves in the acid. Some of the HF formed reacts with the dissolved silica in the reaction: HF reacts with SiO2 to produce H2SiF6 and liquid water.
If 60%wt of hydrofluoric acid was formed when hydrogen fluoride (which exits the reactor) is dissolved in water, determine the amount of ore needed to produce one metric ton of acid.
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VIEWStep 3: Determine SiO2 that reacts with HF to form H2SiF6
VIEWStep 4: Calculate the total amount of HF required to produce the desired amount of hydrofluoric acid
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