Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Acetaldehyde is synthesized by the catalytic dehydrogenation of ethanol:
Fresh feed (pure ethanol) is blended with a recycle stream (95 mole% ethanol and 5%
acetaldehyde), and the combined stream is heated and vaporized, entering the reactor at 280°C.
Gases leaving the reactor are cooled to condense the acetaldehyde and unreacted ethanol. Off-gas
from the condenser is sent to a scrubber, where the uncondensed organic compounds are
removed and hydrogen is recovered as a by-product. The condensate from the condenser, which
is 45 mole% ethanol, is sent to a distillation column that produces a distillate containing 99
mole% acetaldehyde and a bottoms product that constitutes the recycle blended with fresh feed
to the process. The production rate of the distillate is 1000 kg/h. The pressure throughout the
process may be taken as 1 atm absolute.
 
If the vapor leaving the condenser (off-gas to scrubber) is at -40 ̊C and 760 torr, what is the
molar composition of this stream?What assumption are you making when solving this problem?
Feed: C₂H₂OH(1)
CONDENSER
REACTOR
Reactor
output: H₂,
C₂H₂OH(v),
CH,CHO(v)
Recycle
95 mole% C₂H,OH(1)
5 mole% CH,CHO(T)
Off-gas
to scrubber
Condensate
45 mole% C₂H-OH(1)
55 mole
CH,CHO(1)
CONDENSER
Distillate
99 mole% CH,CHOQ)
DISTILLATION
COLUMN
REBOILER
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Transcribed Image Text:Feed: C₂H₂OH(1) CONDENSER REACTOR Reactor output: H₂, C₂H₂OH(v), CH,CHO(v) Recycle 95 mole% C₂H,OH(1) 5 mole% CH,CHO(T) Off-gas to scrubber Condensate 45 mole% C₂H-OH(1) 55 mole CH,CHO(1) CONDENSER Distillate 99 mole% CH,CHOQ) DISTILLATION COLUMN REBOILER
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