Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Acetaldehyde is synthesized by the catalytic dehydrogenation of ethanol:
Fresh feed (pure ethanol) is blended with a recycle stream (95 mole% ethanol and 5%
acetaldehyde), and the combined stream is heated and vaporized, entering the reactor at 280°C.
Gases leaving the reactor are cooled to condense the acetaldehyde and unreacted ethanol. Off-gas
from the condenser is sent to a scrubber, where the uncondensed organic compounds are
removed and hydrogen is recovered as a by-product. The condensate from the condenser, which
is 45 mole% ethanol, is sent to a distillation column that produces a distillate containing 99
mole% acetaldehyde and a bottoms product that constitutes the recycle blended with fresh feed
to the process. The production rate of the distillate is 1000 kg/h. The pressure throughout the
process may be taken as 1 atm absolute.
Fresh feed (pure ethanol) is blended with a recycle stream (95 mole% ethanol and 5%
acetaldehyde), and the combined stream is heated and vaporized, entering the reactor at 280°C.
Gases leaving the reactor are cooled to condense the acetaldehyde and unreacted ethanol. Off-gas
from the condenser is sent to a scrubber, where the uncondensed organic compounds are
removed and hydrogen is recovered as a by-product. The condensate from the condenser, which
is 45 mole% ethanol, is sent to a distillation column that produces a distillate containing 99
mole% acetaldehyde and a bottoms product that constitutes the recycle blended with fresh feed
to the process. The production rate of the distillate is 1000 kg/h. The pressure throughout the
process may be taken as 1 atm absolute.
If the vapor leaving the condenser (off-gas to scrubber) is at -40 ̊C and 760 torr, what is the
molar composition of this stream?What assumption are you making when solving this problem?
molar composition of this stream?What assumption are you making when solving this problem?
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