Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- Potassium fluotitanate (K₂TiF₆), a starting material forproducing other titanium salts, is made by dissolvingtitanium(IV) oxide in concentrated HF, adding aqueous KF, andthen heating to dryness to drive off excess HF. The impure solidis recrystallized by dissolving in hot water and then cooling to 0°C, which leaves excess KF in solution. For the reaction of 5.00 g of TiO₂, 250. mL of hot water is used to recrystallize theproduct. How many grams of purified K₂TiF₆ are obtained?(Solubility of K₂TiF₆ in water at 0°C is 0.60 g/100)arrow_forwardBlast furnace gas is a by-product in converting iron ore to metallic iron using metallurgical coke. A blast furnace gas extracted from a blast furnace is composed of 30% N2, 32% CO, 12% CO2, 8% H₂O and 18% H2. This fuel gas contains high carbon monoxide content and low heating value but can be used as fuel within the steel works and sometimes combined with natural gas to sustain combustion. If 100 mol of the fuel gas is burned with 250 mol of air, what is the percent excess air supplied?arrow_forwardReview | Constants | PeriIodic Table The standard heat of formation, Ar H°, is defined as the enthalpy change for the formation of one mole of substance from its constituent elements in their standard states. Thus, elements in their standard states have AfH® =0. Heat of formation values can be used to calculate the enthalpy change of any reaction. Part A For which of the following reactions is A,H° equal to Ar H° of the product(s)? Consider, for example, the reaction You do not need to look up any values to answer this question. 2NO(g) + O2(9) = 2NO2(9) Check all that apply. with heat of formation values given by the following table: • View Available Hint(s) Substance (kJ mol-1) NO(9) O C(s) + 02 (9)→CO2(9) 90.2 O2 (9) O Li(s) + F2(1)→LIF(s) NO2(9) 33.2 O Li(s) + F2(9)→LİF(s) O 2Li(s) +F2(9)→2LİF(s) Then the heat of formation for the overall reaction is A,H°= EnpAf H° (products)- nA¢H° (reactants) O CO(g) + ÷O2(9)→CO2(9) 2(33.2) [2(90.2) + 0] -114 kJ mol-1 O BaCO3(s)→BA0(s) + CO2(9)…arrow_forward
- Ammonia is oxidized in a continuous reactor 4NH3 g + 5O2 g --> 4NO g + 6H2O g delta AHr= -904.7KJ mol The feed stream (40 mole% NH3 and 60 mole% O2 )enters the reactor at 200 degrees celsius with 80% conversion of ammonia and the products leave at 300 degrees celsius. Determine the quantity of heat required to be added or removed from the reactor.arrow_forwardAmmonia is oxidized in a continuous reactor 4NH3 g + 5O2 g --> 4NO g + 6H2O g delta AHr= -904.7KJ mol The feed stream (40 mole% NH3 and 60 mole% O2 )enters the reactor at 200 degrees celsius with 80% conversion of ammonia and the products leave at 300 degrees celsius. Determine the quantity of heat required to be added or removed from the reactor. The basis of calculation: 10mol/s of feed stream. given: the constant heat capacity, Cp, of NH3(g), O2(g), NO(g), and H2O(v) are 0.035, 0.029, 0.029 and 0.033KJ/ mol. degrees celsius respectively.) Cp O2 or table 8 for the calculation. can you please explaing each steparrow_forwardThe fuel in the form of biogas (65%-mol CH4 and 35%-mol CO2) is burned in a furnace. In order for combustion to take place stoichiometrically, calculate the air to fuel ratio (vol/vol) from this problem!arrow_forward
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