The reaction of sodium borohydride with ketones proceeds rapidly at room temperature, forming an intermediate borate ester which is hydrolyzed to give the product alcohol: 4 R2C=O + Na+BH4- ---> (R2CHO)4B-Na+ (R2CHO)4B-Na+ + 2H2O ---> 4R2CHOH + Na+BO2- Rewrite these two steps using benzil as the ketone, and using structural formulas throughout, rather than the condensed forms above.
The reaction of sodium borohydride with ketones proceeds rapidly at room temperature, forming an intermediate borate ester which is hydrolyzed to give the product alcohol: 4 R2C=O + Na+BH4- ---> (R2CHO)4B-Na+ (R2CHO)4B-Na+ + 2H2O ---> 4R2CHOH + Na+BO2- Rewrite these two steps using benzil as the ketone, and using structural formulas throughout, rather than the condensed forms above.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The reaction of sodium borohydride with
4 R2C=O + Na+BH4- ---> (R2CHO)4B-Na+
(R2CHO)4B-Na+ + 2H2O ---> 4R2CHOH + Na+BO2-
Rewrite these two steps using benzil as the ketone, and using structural formulas throughout, rather than the condensed forms above.
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