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The free radical chlorination of isopentane yields isomeric monochlorinated isopentanes, namely: 1-chloro-2-methybutane; 2-chloro-2-methylbutane; 2-chloro-3-methylbutane; 1-chloro-3-methylbutane. Draw the mechanism and calculate the % yield of each product, assuming that at a specific temperature, the relative reactivities of 3º, 2º, 1° Hydrogen Atoms are in the ratio of 5:3: 1 in free radical chlorination reactions. HH C. CH³\C-C CH3 CH2 H Cl I CH3 HH CIH HCl HH 1 C. CH CH3 C-CH3 CH3 C CH3 CH2 + CH3 CH3 H CH3 H CH H Cl IV III CH3 CI II

The free radical chlorination of isopentane yields isomeric monochlorinated isopentanes, namely: 1-chloro-2-methybutane; 2-chloro-2-methylbutane; 2-chloro-3-methylbutane; 1-chloro-3-methylbutane. Draw the mechanism and calculate the % yield of each product, assuming that at a specific temperature, the relative reactivities of 3º, 2º, 1° Hydrogen Atoms are in the ratio of 5:3: 1 in free radical chlorination reactions. HH C. CH³\C-C CH3 CH2 H Cl I CH3 HH CIH HCl HH 1 C. CH CH3 C-CH3 CH3 C CH3 CH2 + CH3 CH3 H CH3 H CH H Cl IV III CH3 CI II

Physical Chemistry
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter20: Kinetics
Section: Chapter Questions
Problem 20.73E: Determine a rate law for the chlorination of methane assuming that the first step is the...
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The free radical chlorination of isopentane yields isomeric monochlorinated isopentanes, namely: 1-chloro-2-methybutane; 2-chloro-2-methylbutane; 2-chloro-3-methylbutane; 1-chloro-3-methylbutane. Draw the mechanism and calculate the % yield of each product, assuming that at a specific temperature, the relative reactivities of 3º, 2º, 1° Hydrogen Atoms are in the ratio of 5:3: 1 in free radical chlorination reactions. HH C. CH³\C-C CH3 CH2 H Cl I CH3 HH CIH HCl HH 1 C. CH CH3 C-CH3 CH3 C CH3 CH2 + CH3 CH3 H CH3 H CH H Cl IV III CH3 CI II
Transcribed Image Text:The free radical chlorination of isopentane yields isomeric monochlorinated isopentanes, namely: 1-chloro-2-methybutane; 2-chloro-2-methylbutane; 2-chloro-3-methylbutane; 1-chloro-3-methylbutane. Draw the mechanism and calculate the % yield of each product, assuming that at a specific temperature, the relative reactivities of 3º, 2º, 1° Hydrogen Atoms are in the ratio of 5:3: 1 in free radical chlorination reactions. HH C. CH³\C-C CH3 CH2 H Cl I CH3 HH CIH HCl HH 1 C. CH CH3 C-CH3 CH3 C CH3 CH2 + CH3 CH3 H CH3 H CH H Cl IV III CH3 CI II
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