Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Is this reaction mechanism correct?

The image depicts a series of chemical reactions involving chloroalkenes with sodium hydroxide (NaOH).

1. **First Reaction**:
   - A chlorinated alkene (R^1-CH=CH-Cl) is shown reacting with NaOH.
   - The chlorine atom is leaving, forming a hydroxyl group (OH) attached to the alkene chain.
   - Products: An alcohol (HO-R^1-CH=CH) and sodium chloride (NaCl).

2. **Second Reaction**:
   - The same type of chlorinated alkene is depicted.
   - NaOH reacts, leading to the formation of a dehydrohalogenation product.
   - Intermediate steps show electron movement: The base abstracts a proton (H^+), leading to the formation of an alkene with a double bond.
   - Products: An internal alkene (R^1-CH=CH) and byproducts such as Na^+ and H2O.

3. **Third Reaction**:
   - Continuation of the same series of reactions.
   - Further deprotonation occurs, stabilizing the alkene.
   - Products: An alkene (R^1-CH=CH) and hydroxide ion (OH^-).

The diagram illustrates the mechanism of a base-induced elimination reaction, highlighting the nucleophilic substitution and elimination pathways. Curved arrows indicate electron movement, demonstrating the formation and breaking of bonds through the reaction sequence.
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Transcribed Image Text:The image depicts a series of chemical reactions involving chloroalkenes with sodium hydroxide (NaOH). 1. **First Reaction**: - A chlorinated alkene (R^1-CH=CH-Cl) is shown reacting with NaOH. - The chlorine atom is leaving, forming a hydroxyl group (OH) attached to the alkene chain. - Products: An alcohol (HO-R^1-CH=CH) and sodium chloride (NaCl). 2. **Second Reaction**: - The same type of chlorinated alkene is depicted. - NaOH reacts, leading to the formation of a dehydrohalogenation product. - Intermediate steps show electron movement: The base abstracts a proton (H^+), leading to the formation of an alkene with a double bond. - Products: An internal alkene (R^1-CH=CH) and byproducts such as Na^+ and H2O. 3. **Third Reaction**: - Continuation of the same series of reactions. - Further deprotonation occurs, stabilizing the alkene. - Products: An alkene (R^1-CH=CH) and hydroxide ion (OH^-). The diagram illustrates the mechanism of a base-induced elimination reaction, highlighting the nucleophilic substitution and elimination pathways. Curved arrows indicate electron movement, demonstrating the formation and breaking of bonds through the reaction sequence.
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