Suppose the following reaction happening at 25°C Sn(s) + CuSO4(aq) <-----¯ Cu(s) + SNSO4(aq) (reaction in equilibrium) a) Write the left (Anode) and right (Cathode) reactions. b) Calculate the standard cell potential E°Cell- c) Calculate the equilibrium constant “K" of the reaction using the standard potential data table.

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Suppose the following reaction happening at 25°C
Sn(s) + CuSO4(aq)
SNSO4(aq) (reaction in equilibrium)
Cu(s) +
<-----
a) Write the left (Anode) and right (Cathode)
reactions.
b) Calculate the standard cell potential E°Cell·
c) Calculate the equilibrium constant “K" of the
reaction using the standard potential data table.
TABLE 17.1 Standard Reduction Potentials at 25°C (298 K) for Many Common Half-Reactions
Half-Reaction
e (V)
Half-Reaction
e° (V)
F + 2e 2F
Ag* +e - Ag"
Co +e →Cơ
H,O, + 2H + 2e 2H,0
Ce +e → Ce*
PbO, + 4H + so + 2e PbSO, + 2H,0
MnO, + 4H* + 3e MnO, + 2H,O
2e + 2H + IO, 10, + H,0
MnO, + 8H + Se" → Mn* + 4H,0
Au + 3e -→ Au
PbO, + 4H + 2e Pb* + 2H,O
Ca, + 2e" → 2CI"
Cr0,- + 14H + 6e" → 2Cr“ + 7H,0
O, + 4H + 4e 2H,O
MnO, + 4H + 2e Mn + 2H,O
10, + 6H + Se → I, + 3H,0
Br, + 2e 2Br
-2H +e VO + H,O
2.87
1.99
O, + 2H,0 + 4c → 40H
Cu + 2e Cu
Hg,Cl, + 2e -→ 2Hg + 2CI
AgCI +e Ag + CI
so- + 4H + 2e → H,SO, + H,O
Cu* + e - Cu*
2H + 2e H;
Fe + 3e Fe
Pb* + 2e" -→ Pb
Sn
Ni* + 2e Ni
PbSO, + 2e - Pb + So,-
Cd + 2e -→ Cd
Fe* + 2e Fe
Cr* +e Cr*
Cr + 3e → Cr
Zn* + 2e - Zn
0.40
0.34
1.82
0.27
1.78
0.22
1.70
0.20
1.69
1.68
0.16
0,00
1.60
-0.036
1.51
-0.13
2e Sn
1.50
1.46
1.36
-0.14
-0.23
-0.35
-0.40
1.33
1.23
-0,44
1.21
-0,50
1.20
-0.73
1.09
-0.76
-0.83
VO,
AuCl, + 3e → Au + 4CI
NO, + 4H + 3e NO + 2H,O
CIO, +e → CIO,
2Hg* + 2e Hg,*
Ag +e → Ag
Hg, + 2e 2Hg
Fe +e → Fe*
O, + 2H* + 2e" → H;O;
MnO, +e -→ MnO,
I, + 2e 21
Cu +e Cu
1.00
2H,0 + 2e - H, + 20H
Mn + 2e"- Mn
Al + 3e → Al
H + 2e 2H
Mg + 2e Mg
La + 3e -→ La
Na + e → Na
Ca + 2e -→ Ca
Ba + 2e" - Ba
-1.18
-1.66
0.99
0.96
0.954
-2.23
-2.37
-2.37
-2.71
-2.76
0.91
0,80
0.80
0.77
0.68
-2.90
0.56
K* +e - K
-2.92
0.54
Li +e Li
-3.05
0.52
Transcribed Image Text:Suppose the following reaction happening at 25°C Sn(s) + CuSO4(aq) SNSO4(aq) (reaction in equilibrium) Cu(s) + <----- a) Write the left (Anode) and right (Cathode) reactions. b) Calculate the standard cell potential E°Cell· c) Calculate the equilibrium constant “K" of the reaction using the standard potential data table. TABLE 17.1 Standard Reduction Potentials at 25°C (298 K) for Many Common Half-Reactions Half-Reaction e (V) Half-Reaction e° (V) F + 2e 2F Ag* +e - Ag" Co +e →Cơ H,O, + 2H + 2e 2H,0 Ce +e → Ce* PbO, + 4H + so + 2e PbSO, + 2H,0 MnO, + 4H* + 3e MnO, + 2H,O 2e + 2H + IO, 10, + H,0 MnO, + 8H + Se" → Mn* + 4H,0 Au + 3e -→ Au PbO, + 4H + 2e Pb* + 2H,O Ca, + 2e" → 2CI" Cr0,- + 14H + 6e" → 2Cr“ + 7H,0 O, + 4H + 4e 2H,O MnO, + 4H + 2e Mn + 2H,O 10, + 6H + Se → I, + 3H,0 Br, + 2e 2Br -2H +e VO + H,O 2.87 1.99 O, + 2H,0 + 4c → 40H Cu + 2e Cu Hg,Cl, + 2e -→ 2Hg + 2CI AgCI +e Ag + CI so- + 4H + 2e → H,SO, + H,O Cu* + e - Cu* 2H + 2e H; Fe + 3e Fe Pb* + 2e" -→ Pb Sn Ni* + 2e Ni PbSO, + 2e - Pb + So,- Cd + 2e -→ Cd Fe* + 2e Fe Cr* +e Cr* Cr + 3e → Cr Zn* + 2e - Zn 0.40 0.34 1.82 0.27 1.78 0.22 1.70 0.20 1.69 1.68 0.16 0,00 1.60 -0.036 1.51 -0.13 2e Sn 1.50 1.46 1.36 -0.14 -0.23 -0.35 -0.40 1.33 1.23 -0,44 1.21 -0,50 1.20 -0.73 1.09 -0.76 -0.83 VO, AuCl, + 3e → Au + 4CI NO, + 4H + 3e NO + 2H,O CIO, +e → CIO, 2Hg* + 2e Hg,* Ag +e → Ag Hg, + 2e 2Hg Fe +e → Fe* O, + 2H* + 2e" → H;O; MnO, +e -→ MnO, I, + 2e 21 Cu +e Cu 1.00 2H,0 + 2e - H, + 20H Mn + 2e"- Mn Al + 3e → Al H + 2e 2H Mg + 2e Mg La + 3e -→ La Na + e → Na Ca + 2e -→ Ca Ba + 2e" - Ba -1.18 -1.66 0.99 0.96 0.954 -2.23 -2.37 -2.37 -2.71 -2.76 0.91 0,80 0.80 0.77 0.68 -2.90 0.56 K* +e - K -2.92 0.54 Li +e Li -3.05 0.52
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