Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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The following system is at equilibrium in a closed vessel:
2 CH4(g) ⇆ C2H6(g) + H2(g)
Various stresses are applied to the system as illustrated in the chart. Drag the appropriate label from the list below that indicates how the system responds to each stress. Each label can be used more than once.
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Transcribed Image Text:Unit 42-Le Chateliers Principle X
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Stress
Increase pressure
Add H₂(g)
Remove C₂H₂(g)
Add CH₂(g)
Decrease volume
02 is removed from the followin
Response of
system to stress
unchanged
shifts left
shifts left
shifts right
shifts left
shifts left shifts right unchanged
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952 AM
2/15/2023
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- While ethanol (CH3CH,OH) is produced naturally by fermentation, e.g. in beer- and wine-making, industrially it is synthesized by reacting ethylene (CH,CH,) with water vapor at elevated temperatures. A chemical engineer studying this reaction fills a 500. mL flask with 0.77 atm of ethylene gas and 0.98 atm of water vapor. When the mixture has come to equilibrium he determines that it contains 0.34 atm of ethylene gas and 0.55 atm of water vapor. The engineer then adds another 0.19 atm of ethylene, and allows the mixture to come to equilibrium again. Calculate the pressure of ethanol after equilibrium is reached the second time. Round your answer to 2 significant digits. atmarrow_forwardAt a certain temperature, the reaction: PCl5(g) ⇆ PCl3(g) + Cl2(g) has an equilibrium constant Kc = 6.7E-6. Calculate the equilibrium concentration of PCl3 if only PCl5 is present initially at a concentration of 0.30 M. Your answer should have two significant figures.arrow_forwardAt a certain temperature, the reaction: PCl5(g) ⇆ PCl3(g) + Cl2(g) has an equilibrium constant Kc = 6.7E-6. Calculate the equilibrium concentration of PCl3 if only PCl5 is present initially at a concentration of 0.30 M. Your answer should have two significant figures.arrow_forward
- A closed 1.00 L system initially containing 0.00200 mol H₂ and 0.00500 mol 1₂ at a given temperature is allowed to reach equilibrium Analysis of the equilibrium mixture shows that the amount of HI present at equilibrium is 0.00371 mol. Calculate the Kc at this temperature for the reaction. State whether the equilibrium is product-favored or reactant- favored at this temperature. H₂(g) +1₂(g) 2H1(g) Kc 31: The equilibrium is product-favored. Kc 31: The equilibrium is reactant-favored. Kc 0.032; The equilibrium is reactant-favored. Kc - 0.032; The equilibrium is product-favored.arrow_forwardPhosphorous pentachloride decomposes according to the reaction PCl5(g)↽−−⇀PCl3(g)+Cl2(g)PCl5(g)↽−−⇀PCl3(g)+Cl2(g) A 13.1 gsample of PCl5 is added to a sealed 1.25 L flask and the reaction is allowed to come to equilibrium at a constant temperature. At equilibrium, 48.4% of the PCl5 remains. What is the equilibrium constant, Kc , for the reaction?arrow_forwardMethane and water react to form carbon monoxide and hydrogen, like this: CH2(g)+H₂O(g) CO(g)+3H2(g) Suppose a mixture of CH 4, H2O, CO and H2 has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation change in composition shift in equilibrium to the right The pressure of CH4 will ? to the left Some CO is added. The pressure of H2O will ? (none) to the right The pressure of H2O will ? Some CH4 is removed. to the left The pressure of CO will ? (none)arrow_forward
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