Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
Bartleby Related Questions Icon

Related questions

bartleby

Concept explainers

Question

Oh my gosh, it's been 3 HOURS... PLEASE SOMEONE JUST HELP EXPLAIN THIS... WHY IS IT SO HARD TO FIND ACTUAL HELP ON THIS WEBSITE... CHEGG WOULD HAVE DONE THIS IN 30 MINS!!!

### Spectroscopy Unknown

The spectra and data provided were obtained from a pure organic molecule.

#### Mass Spectrum (not shown):
- **[M] = 177 (100%) m/z**

#### IR Spectrum (not shown):
- **Key Absorption Bands** (all listed are strong unless otherwise indicated):
  - 3200 (sh m)
  - 3060
  - 2981
  - 1685
  - 1600
  - 1495 cm⁻¹

#### ¹H NMR Spectrum (400 MHz, CDCl₃, 25 °C)

The ¹H NMR spectrum displays the following peaks:

- **0.9 ppm**: Singlet (s), corresponding to 6 hydrogens.
- **1.7 ppm**: Doublet (d), corresponding to 3 hydrogens.
- **2.2 ppm**: Multiplet (m), corresponding to 1 hydrogen.
- **6.5 ppm**: Doublet (d), corresponding to 2 hydrogens.
- **7.3 ppm**: Doublet (d), corresponding to 2 hydrogens.
- **10 ppm**: Broad singlet (br s), corresponding to 1 hydrogen.

#### ¹³C NMR Spectrum, proton-decoupled (125 MHz, CDCl₃, 25 °C)

The ¹³C NMR spectrum illustrates:

- **20 ppm**: (CH₃)
- **30 ppm**: (CH₃)
- **50 ppm**: (CH)
- **70 ppm**: (CH)
- **120 ppm**: (CH)
- **130 ppm**: (CH)
- **140 ppm**: (C)
- **160 ppm**: (C)
- **170 ppm**: (C)

This data assists in identifying the molecular structure by providing information on the number and types of hydrogen and carbon environments present in the molecule. The integration of peaks in the ¹H NMR spectrum corresponds to the number of hydrogens, while the splitting patterns (singlets, doublets, multiplets) offer insight into the hydrogen’s neighboring atoms. Similarly, the ¹³C NMR spectrum reveals distinct carbon environments within the compound.
expand button
Transcribed Image Text:### Spectroscopy Unknown The spectra and data provided were obtained from a pure organic molecule. #### Mass Spectrum (not shown): - **[M] = 177 (100%) m/z** #### IR Spectrum (not shown): - **Key Absorption Bands** (all listed are strong unless otherwise indicated): - 3200 (sh m) - 3060 - 2981 - 1685 - 1600 - 1495 cm⁻¹ #### ¹H NMR Spectrum (400 MHz, CDCl₃, 25 °C) The ¹H NMR spectrum displays the following peaks: - **0.9 ppm**: Singlet (s), corresponding to 6 hydrogens. - **1.7 ppm**: Doublet (d), corresponding to 3 hydrogens. - **2.2 ppm**: Multiplet (m), corresponding to 1 hydrogen. - **6.5 ppm**: Doublet (d), corresponding to 2 hydrogens. - **7.3 ppm**: Doublet (d), corresponding to 2 hydrogens. - **10 ppm**: Broad singlet (br s), corresponding to 1 hydrogen. #### ¹³C NMR Spectrum, proton-decoupled (125 MHz, CDCl₃, 25 °C) The ¹³C NMR spectrum illustrates: - **20 ppm**: (CH₃) - **30 ppm**: (CH₃) - **50 ppm**: (CH) - **70 ppm**: (CH) - **120 ppm**: (CH) - **130 ppm**: (CH) - **140 ppm**: (C) - **160 ppm**: (C) - **170 ppm**: (C) This data assists in identifying the molecular structure by providing information on the number and types of hydrogen and carbon environments present in the molecule. The integration of peaks in the ¹H NMR spectrum corresponds to the number of hydrogens, while the splitting patterns (singlets, doublets, multiplets) offer insight into the hydrogen’s neighboring atoms. Similarly, the ¹³C NMR spectrum reveals distinct carbon environments within the compound.
Expert Solution
Check Mark
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY