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Show what alcohol will undergo acid catalyzed condensation, with loss of water, to give 1,4-dioxane
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- Predict the alcohol products of the hydration, hydroboration, and dihydroxylation of alkenes.Acid-catalyzed dehydration of secondary and tertiary alcohols proceeds through an E1 mechanism. The first step is the protonation of the alcohol oxygen to form an oxonium ion. Dehydration of 3-methyl-2-butanol forms one major and two minor organic products. Draw the structures, including hydrogen atoms, of the three organic products of this reaction. н н :бн н Нас. Нас. CHз CH3 ČH3 CH3 3-methyl-2-butanol an oxonium ion Major Product Minor Product Minor ProductEsterication is the reaction of a carboxylic acid (RCOOH) with an alcohol (R'OH) to form an ester (RCOOR') with loss of water. Equation [1] is an example of an intermolecular esterication reaction. Equation [2] is an example of an intramolecular esterication reaction; that is, the carboxylic acid and alcohol are contained in the same starting material, forming a cyclic ester as product. The equilibrium constants for both reactions are given. Explain why Keq is different for these two apparently similar reactions.
- 2. Using structural diagrams to explain the synthesis of butyl ethanoate from an alkane and an alcohol. Make sure you have the names of the substances and the reaction conditions of the reactions of the steps that consists your synthesis HC-C H- styrene HH ethane-1,2-diol OH НО. JOL -0-H benzene-1.4-dicarboxylic acid.Do primary, secondary, or tertiary alcohols undergo rearrangement upon conversion to the alkyl halides?Which compound is a tertiary alcohol that may not be oxidized by H2CrO4 or MnO2? Which compound is a secondary alcohol that may be oxidized to a ketone by MnO2? Which compound is an alcohol that may be oxidized to an aldehyde by PCC?
- 2-chloropropane is a major product of the reaction of chlorine with propane under ultraviolet light. Write the mechanism for this reaction including the initiation step and the two propagation steps.1,4-Dioxane is made commercially by the acid-catalyzed condensation of an alcohol.(a) Show what alcohol will undergo condensation, with loss of water, to give 1,4-dioxane.Alkenes can be converted to alcohols by reaction with mercuric acetate to form a β-hydroxyalkylmercury(II) acetate compound, a reaction called oxymercuration. Subsequent reduction with NaBH4 reduces the C–Hg bond to a C–H bond, forming the alkyl alcohol, a reaction called demercuration. Draw the structures of the Hg-containing compound(s) and the final alcohol product(s) formed in the following reaction sequence, omitting byproducts. If applicable, draw hydrogen at a chirality center and indicate stereochemistry via wedge-and-dash bonds.
- Alkenes can be converted to alcohols by reaction with mercuric acetate to form a ß-hydroxyalkylmercury(II) acetate compound, a reaction called oxymercuration. Subsequent reduction with NaBH reduces the C-Hg bond to a C-H bond, forming the alkyl alcohol, a reaction called demercuration. Draw the structure of the Hg-containing compound and the final alcohol product formed in the reaction sequence. CH3 Hg(OOCCH3)2 NaBH4 HO™ Oxymercuration product Demercuration Product H₂O, THF Draw the alcohol product of demercuration. Draw the neutral product of oxymercuration. Omit byproducts. OH Hg IncorrectDrinking of too much alcohol cause liver cirrhosis because ethanol is converted to toxic * Acetone Ethanal Acetic acid Methyl ethanoate Ethers have lower boiling points compared to alcohols of comparable mass because they form dipole-dipole interaction among themselves. they cannot form hydrogen bond among themselves. they can form hydrogen bond with water. they are solvents in organic reactions. Dehydration of two molecules of methanol under acidic condition (H2SO4) at high temperature will produce * Acetone Ethanal Acetic acid MethoxymethaneCompounds X and Y have the formula C6H12- Both X and Y react with one molar equivalent of hydrogen in the presence of a palladium catalyst to form 2-methylpentane. The heat of hydrogenation of X is less than that of Y. X and Y react with HBr to form a mixture of the same bromoalkanes, and they both undergo hydroboration/oxidation to give a mixture of the same alcohols. What is the structure of Y? In cases where there is more than one answer, just draw one. n. n [ ]# ChemDoodleⓇ za