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Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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show that the Hamiltonian operator for the total energy of a system is hermitian provided that the eigenfunction is well behaved
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- Hi I need help on one of my physical chemistry questions and I don't know how to do it. Will you please help me solve for it thank you very much!arrow_forwardFor the particle in the 1D box, the system approaches classical behavior as the spacing between energy levels (dE) for a change in level (dn) approaches zero, i.e. dE / dn = 0. Under what circumstances does this happen?arrow_forwardConsider the three spherical harmonics (a) Y0,0, (b) Y2,–1, and (c) Y3,+3. (a) For each spherical harmonic, substitute the explicit form of the function taken from Table 7F.1 into the left-hand side of eqn 7F.8 (the Schrödinger equation for a particle on a sphere) and confirm that the function is a solution of the equation; give the corresponding eigenvalue (the energy) and show that it agrees with eqn 7F.10. (b) Likewise, show that each spherical harmonic is an eigenfunction of lˆz = (ℏ/i)(d/dϕ) and give the eigenvalue in each case.arrow_forward
- Do the kinetic energy operator and momentum operator commute once they are applied on f(x) =AX? Select one: O a. Yes they do commute O b. They don't commute O c. No clear conclusion could be drawn O d. Nonearrow_forwardWhat is lambdamax and how was it determined?arrow_forwardWithout evaluating any integrals, state the value of the expectation value of x for a particle in a box of length L for the case where the wavefunction has n = 2. Explain how you arrived at your answer.arrow_forward
- Evaluate the linear momentum and kinetic energy of a free electron described by the wavefunction eikx with k = 3 nm−1.arrow_forward2. Show that the set of one-dimensional particle in the box functions where n = 1,2,3... are orthonormal.arrow_forward1. We've looked at the particle in a box, particle on a circle, and the harmonic oscillator What was the source of quantization in each case?arrow_forward
- Using the wavefunctions for the particle in 1D box, show that the Hamiltonian is (a) a linear operator, and (b) Hermitian.arrow_forward1) The following questions concern commutation relations, by applying it to an arbitrary function.arrow_forwardWrite the total wavefunction (Slater Determinant) for Be atom (4 electrons)arrow_forward
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